{"id":"W2035189450","doi":"10.1139/v01-005","title":"The syntheses of 6-<i>C</i>-alkyl derivatives of methyl α-isomaltoside for a study of the mechanism of hydrolysis by amyloglucosidase","year":2001,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Enzyme Production and Characterization","field":"Biochemistry, Genetics and Molecular Biology","cited_by":8,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Hydrolysis; Hydrogen bond; Isopropyl; Alkyl; Stereochemistry; Glycosidic bond; Medicinal chemistry; Molecule; Organic chemistry; Enzyme","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001673544,0.0003565989,0.0002834871,0.0001662305,0.0001297827,0.0001536016,0.0003230128,0.0002795815,0.0009263009],"category_scores_gemma":[0.0002471862,0.0001450985,0.0003329707,0.00036228,0.0001324902,0.0002835404,0.0002223046,0.000723246,0.0007068608],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001635565,"about_ca_system_score_gemma":0.0002863398,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002287172,"about_ca_topic_score_gemma":0.0003629556,"domain_scores_codex":[0.9998221,0.00003879957,0.00002739972,0.00002261013,0.00005110731,0.00003797908],"domain_scores_gemma":[0.9997447,0.00002427871,0.00008615205,0.0000331473,0.00006514178,0.00004647253],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000727678,0.00002910805,0.00009392844,0.0001086917,0.000006250074,0.00009975342,0.00003648983,0.0003192661,0.9964078,0.0002450332,0.00002399497,0.002556841],"study_design_scores_gemma":[0.000008701941,0.0003705103,0.000582758,0.0000057042,0.00001322428,0.0001348115,0.00001389304,0.0003365921,0.9964641,0.00004937607,0.002012369,0.000008003541],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.974667,0.002585888,0.01710401,0.0001047095,0.00007043908,0.0001811761,0.0005754133,0.00007684864,0.004634606],"genre_scores_gemma":[0.9748736,0.00275247,0.01881592,0.00006168071,0.00002739209,0.0001490465,0.0008019613,0.00006857776,0.002449351],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0009263009,"threshold_uncertainty_score":0.003098845,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008843070946845572,"score_gpt":0.2191806852983854,"score_spread":0.2103376143515399,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}