{"id":"W2035273074","doi":"10.1021/om060874f","title":"Electronic Effects in PCP-Pincer Ru(II)-Based Hydrogen Transfer Catalysis","year":2007,"lang":"en","type":"article","venue":"Organometallics","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":59,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Ruthenium; Pincer movement; Catalysis; Hydride; Trifluoromethanesulfonate; Cyclohexanone; Medicinal chemistry; Cyclohexanol; Pincer ligand; Ligand (biochemistry); Transfer hydrogenation; Stereochemistry; Combinatorial chemistry; Metal; Organic chemistry","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0005657132,0.0003196858,0.0004324784,0.0006254499,0.0001359506,0.00002950504,0.0004204342,0.0002608534,0.003618716],"category_scores_gemma":[0.0001202377,0.0003255739,0.0002956171,0.002768212,0.00006652344,0.0001290311,0.00004969609,0.0003702221,0.0002289427],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005161716,"about_ca_system_score_gemma":0.0001745854,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00007794648,"about_ca_topic_score_gemma":0.000408489,"domain_scores_codex":[0.9976408,0.00002432405,0.0005084971,0.0005228196,0.000510207,0.0007933014],"domain_scores_gemma":[0.9989303,0.0001691048,0.00007079623,0.0005674338,0.00006100613,0.0002013998],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002256277,0.002916407,0.0225021,0.0006056275,0.001462319,0.000282077,0.001339298,0.001507329,0.8390616,0.005094759,0.000147949,0.1248549],"study_design_scores_gemma":[0.001573487,0.00004520856,0.0006862063,0.00001753871,0.0002118887,0.000006792398,0.00006364146,0.001358266,0.9637712,0.0001557589,0.03156994,0.000540114],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9798781,0.0009334796,0.005827452,0.0001455134,0.00003425094,0.0001254829,0.00001110624,0.0001476971,0.01289696],"genre_scores_gemma":[0.9963113,0.00005281732,0.00008948962,0.0003136157,0.00008360256,0.00002822121,0.0003139428,0.00006806115,0.002738937],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1247096,"threshold_uncertainty_score":0.9999197,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004673229107970266,"score_gpt":0.213991523749444,"score_spread":0.2093182946414737,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}