{"id":"W2035301496","doi":"10.1021/ja017418x","title":"Stereoselective Recognition of an Aziridine with a Co(III) Complex:  A Potential Transition-State Analogue for Catalytic Epoxidation","year":2002,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Synthesis and Catalytic Reactions","field":"Chemistry","cited_by":27,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Aziridine; Chemistry; Stereoselectivity; Cyclohexane; Ligand (biochemistry); Stereochemistry; Salicylaldehyde; Catalysis; Molecule; Solid-state; Organic chemistry; Ring (chemistry); Physical chemistry; Receptor","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009937034,0.0001525994,0.0002143886,0.00005699954,0.0001114618,0.0003030043,0.0003299702,0.0002505475,0.0004764149],"category_scores_gemma":[0.0001524918,0.0001111625,0.0001171433,0.00005912194,0.0002332824,0.0001239579,0.0001411827,0.000312051,0.0001561123],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003170191,"about_ca_system_score_gemma":0.0001123453,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005104739,"about_ca_topic_score_gemma":0.0008159233,"domain_scores_codex":[0.9999286,0.00001127287,0.000003620967,0.00002253656,0.00002081234,0.00001317523],"domain_scores_gemma":[0.9999484,0.00001133623,0.00001285583,0.000009249433,0.000006627163,0.0000114643],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009249427,0.00002075147,0.0001222113,0.0000274186,0.000004431409,0.00007438286,0.00002984623,0.0002719017,0.9976479,0.0003720179,0.00004238604,0.001294212],"study_design_scores_gemma":[0.00002190925,0.0001107279,0.0003252599,0.000001006985,0.000004367794,0.0001043867,0.000008300379,0.002058081,0.996582,0.00003297869,0.0007476049,0.000003409198],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9955382,0.0002339522,0.002608349,0.00005256593,0.00001003076,0.00001489298,0.00002813673,0.00005059191,0.001463157],"genre_scores_gemma":[0.9979048,0.00009007333,0.001317223,0.00001211547,0.00000176076,0.000005433153,0.00003509244,0.000006954598,0.0006265262],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0005104739,"threshold_uncertainty_score":0.002300143,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02360401625392827,"score_gpt":0.251305716817515,"score_spread":0.2277017005635867,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}