{"id":"W2035491583","doi":"10.1021/ja070828m","title":"Chemical Modification of Monolayer-Protected Gold Nanoparticles Using Hyperbaric Conditions","year":2007,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Gold and Silver Nanoparticles Synthesis and Applications","field":"Materials Science","cited_by":34,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Maleimide; Steric effects; Colloidal gold; Monolayer; Nanoparticle; Electronic effect; Combinatorial chemistry; Nanotechnology; Chemical engineering; Organic chemistry; Biochemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002261465,0.0004684209,0.0002041455,0.0001657085,0.0001732371,0.0001880911,0.0004032627,0.0002616342,0.001355366],"category_scores_gemma":[0.0002556384,0.0002857083,0.0002172664,0.0001094265,0.0002848779,0.000285359,0.0002781813,0.0004840739,0.0004442772],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00033278,"about_ca_system_score_gemma":0.0001409866,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003965053,"about_ca_topic_score_gemma":0.0009998307,"domain_scores_codex":[0.9998386,0.00002152055,0.00001208008,0.00005294447,0.00004706764,0.00002777317],"domain_scores_gemma":[0.9998784,0.00002948157,0.00002437521,0.00003126891,0.00002052414,0.00001601506],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001715191,0.000004736163,0.00002232134,0.00002080347,0.000002794717,0.00001702467,0.00001184155,0.0000348038,0.9992729,0.00004864635,0.00001647531,0.0005305849],"study_design_scores_gemma":[0.00000208864,0.00003434567,0.0002068514,0.00000102951,0.000002878796,0.00003029755,0.000004049123,0.0001215914,0.9991719,0.00001159342,0.0004120267,0.000001370491],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9800754,0.0008981688,0.01486122,0.0001055812,0.00007025716,0.00008195374,0.000157787,0.0002155457,0.00353412],"genre_scores_gemma":[0.9839395,0.0008442249,0.01078653,0.00008555137,0.00001360562,0.00007912813,0.0002998595,0.00005642394,0.003895207],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001355366,"threshold_uncertainty_score":0.004534185,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02787884666108517,"score_gpt":0.2807801992565388,"score_spread":0.2529013525954537,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}