{"id":"W2035503485","doi":"10.1023/b:jtan.0000011022.51234.19","title":"Thermal and spectral properties of halogenosalicylato-Cu(II) complexes","year":2003,"lang":"en","type":"article","venue":"Journal of Thermal Analysis and Calorimetry","topic":"Inorganic and Organometallic Chemistry","field":"Chemistry","cited_by":21,"is_retracted":false,"has_abstract":false,"ca_institutions":"Mount Allison University","funders":"","keywords":"Complexometric titration; Chemistry; Thermal analysis; Thermal stability; Copper; Denticity; Thermal decomposition; Molecule; Electron paramagnetic resonance; Titration; Thermogravimetry; Infrared spectroscopy; Elemental analysis; Differential thermal analysis; Inorganic chemistry; Coordination complex; Physical chemistry; Thermal; Metal; Crystallography; Crystal structure; Organic chemistry; Nuclear magnetic resonance; Thermodynamics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002887766,0.0001930376,0.0006369981,0.000136574,0.0001247286,0.00003266836,0.0001694597,0.0001159517,0.001319727],"category_scores_gemma":[0.00006145471,0.0001345477,0.0003223923,0.0003376516,0.0001965978,0.0001070152,0.00006077447,0.0002534662,8.466305e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002750738,"about_ca_system_score_gemma":0.00005692631,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0000553141,"about_ca_topic_score_gemma":0.0000041274,"domain_scores_codex":[0.9987325,0.00003294838,0.0005759076,0.0001667466,0.0002820472,0.0002098503],"domain_scores_gemma":[0.9990819,0.00003145972,0.0004408674,0.0001840949,0.0001207455,0.0001409203],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006164291,0.0001120369,0.04712508,0.00009034101,0.001729368,0.00001236299,0.0003207275,0.00001902257,0.9498242,0.0002244374,0.00001235037,0.0004684629],"study_design_scores_gemma":[0.0005221498,0.00005126982,0.01024838,0.00003010276,0.001484199,0.0000764216,0.0006135641,0.00005038222,0.9863095,0.00005910408,0.000373762,0.0001811385],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9902966,0.006102647,0.00003950735,0.00004828753,0.00003058607,0.00001444064,0.000008134122,0.000006242014,0.003453581],"genre_scores_gemma":[0.9988487,0.0001616464,0.0002477944,0.00003303542,0.0001607874,3.119906e-7,0.000001758827,0.00001513075,0.0005308606],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0368767,"threshold_uncertainty_score":0.9995932,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01177286783696768,"score_gpt":0.2060547016247183,"score_spread":0.1942818337877507,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}