{"id":"W2035504896","doi":"10.1063/1.1926284","title":"Fourier transform microwave spectroscopy of HSiBr: Exploring the Si–Br bond through quadrupole hyperfine coupling","year":2005,"lang":"en","type":"article","venue":"The Journal of Chemical Physics","topic":"Molecular Spectroscopy and Structure","field":"Chemistry","cited_by":6,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"","keywords":"Quadrupole; Rotational spectroscopy; Hyperfine structure; Chemistry; Coupling constant; Isotopomers; Analytical Chemistry (journal); Ab initio quantum chemistry methods; Ionic bonding; Atomic physics; Molecular physics; Nuclear magnetic resonance; Physics; Molecule; Ion; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002181051,0.0002330192,0.0003919333,0.0000111871,0.0001016164,0.00002570574,0.0005934659,0.00008419176,0.00009960595],"category_scores_gemma":[0.00002572129,0.0001352873,0.0003129618,0.0001419886,0.0002153634,0.0002163742,0.00004596204,0.0009195425,0.000003460691],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00008430721,"about_ca_system_score_gemma":0.00007053396,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000006159312,"about_ca_topic_score_gemma":0.00000122955,"domain_scores_codex":[0.9984967,0.00001247162,0.0005528617,0.0001227145,0.0004898296,0.0003254733],"domain_scores_gemma":[0.9988863,0.0001558817,0.0003901057,0.000388474,0.0001074583,0.00007175981],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002917805,0.00007193459,0.00001327742,0.00004956718,0.0001196147,0.000002991496,0.001490291,0.0003934839,0.9946567,0.0007995735,0.0004137901,0.001696944],"study_design_scores_gemma":[0.0005675422,0.00005099182,0.000003268965,0.0000906843,0.0001747653,0.00007561337,0.0002357535,0.0007229429,0.9843729,0.0118172,0.00174207,0.0001462666],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9878126,0.0008465744,0.006347138,0.001331397,0.0001010094,0.00005388266,0.000008648289,0.00001213319,0.003486584],"genre_scores_gemma":[0.9914189,0.0002594584,0.005966032,0.0001671996,0.002105246,0.000001888965,0.000002606757,0.00003643601,0.00004224868],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01101762,"threshold_uncertainty_score":0.5516856,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01770414236260122,"score_gpt":0.2510008354127066,"score_spread":0.2332966930501054,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}