{"id":"W2035599118","doi":"10.1021/ma0708139","title":"Verdazyl-Mediated Living-Radical Polymerization of Styrene and <i>n</i>-Butyl Acrylate","year":2007,"lang":"en","type":"article","venue":"Macromolecules","topic":"Advanced Polymer Synthesis and Characterization","field":"Chemistry","cited_by":38,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Polymer chemistry; Radical polymerization; Styrene; Copolymer; Polymerization; Living free-radical polymerization; Chemistry; Cobalt-mediated radical polymerization; Acrylate; Living polymerization; Benzoyl peroxide; Nitroxide mediated radical polymerization; Dispersity; Reversible addition−fragmentation chain-transfer polymerization; Polymer; Photochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001014719,0.0001530725,0.0001944696,0.00005870828,0.00006417837,0.00001926915,0.0001047618,0.0001195617,0.0003338631],"category_scores_gemma":[0.0001044943,0.0001541692,0.0000418431,0.0001304968,0.0001274617,0.00009092067,0.00006204128,0.00008514725,0.000006211257],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001436039,"about_ca_system_score_gemma":0.00001666496,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001920486,"about_ca_topic_score_gemma":0.000006135632,"domain_scores_codex":[0.9990075,0.00001486146,0.0003213775,0.0002275838,0.0001845166,0.0002441536],"domain_scores_gemma":[0.9993511,0.0001541003,0.0001742336,0.0001857087,0.00003212582,0.000102761],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003462002,0.00006278449,0.004588712,0.00005888267,0.000021762,0.000009684702,0.0002453638,0.000001016705,0.9621201,0.000247674,0.000004954977,0.03260449],"study_design_scores_gemma":[0.0002234841,0.00002130581,0.006612191,0.00009739633,0.00002320336,0.00001307385,0.0001074996,0.0002314319,0.9914677,0.00003893761,0.0009825098,0.0001812703],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9888027,0.0007527039,0.007478414,0.00005651269,0.00005322388,0.00003457279,0.00005466203,0.00007196629,0.002695206],"genre_scores_gemma":[0.999006,0.0001768945,0.0003612527,0.00008017936,0.00007599875,0.000003291071,0.00009255947,0.00003060012,0.0001732426],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03242321,"threshold_uncertainty_score":0.6286837,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005369630309964901,"score_gpt":0.2183748020383509,"score_spread":0.213005171728386,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}