{"id":"W2035620365","doi":"10.1021/ic9910561","title":"Complexation of Co(DBF<sub>2</sub>)<sub>2</sub> by <i>N</i>-Methylimidazole in Acetonitrile:  Formation Constants and <sup>1</sup>H NMR Shifts and Relaxation Times","year":2000,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Porphyrin Metabolism and Disorders","field":"Biochemistry, Genetics and Molecular Biology","cited_by":4,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"","keywords":"Chemistry; Acetonitrile; Titration; Chemical shift; Relaxation (psychology); Ligand (biochemistry); Equilibrium constant; Physical chemistry; Nuclear magnetic resonance spectroscopy; Analytical Chemistry (journal); Inorganic chemistry; Stereochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0002413122,0.0002649397,0.0002936443,0.00004391272,0.00009121084,0.0000376445,0.0001359399,0.0003275801,0.00004610055],"category_scores_gemma":[0.0001129278,0.0002931199,0.00004770755,0.0001972877,0.0002111223,0.00004469531,0.00006620315,0.0001685079,0.000008925655],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002709452,"about_ca_system_score_gemma":0.0000838885,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001612162,"about_ca_topic_score_gemma":0.000009378931,"domain_scores_codex":[0.9985265,0.00006286785,0.0004794341,0.0004234904,0.0002092126,0.0002985523],"domain_scores_gemma":[0.9992483,0.00003623181,0.0002342548,0.0002895682,0.00007474509,0.0001169047],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001157185,0.00008605485,0.002507687,0.000126473,0.00002411774,0.000001259612,0.0002787347,0.00005031925,0.984524,0.000005963105,0.001432802,0.01084693],"study_design_scores_gemma":[0.001780698,0.00003956395,0.004171842,0.0000407017,0.00003289187,0.00002711732,0.0002748242,0.0004751988,0.9915008,0.0001459363,0.001207187,0.0003032241],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9960271,0.002434636,0.0001032639,0.00006178206,0.00001347547,0.0002302042,0.0001747209,0.0000228067,0.0009320753],"genre_scores_gemma":[0.9951673,0.003509621,0.00004995566,0.0001257071,0.00005810303,0.00001703388,0.00101844,0.00002817933,0.00002567115],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01054371,"threshold_uncertainty_score":0.9999521,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004259279087758789,"score_gpt":0.2031573896195254,"score_spread":0.1988981105317666,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}