{"id":"W2035672001","doi":"10.1021/ol703135w","title":"Synthesis of Morpholin-2-ones by Chemoselective Intramolecular Rhodium-Catalyzed Reductive Ring Expansion of Oxazolidines","year":2008,"lang":"en","type":"article","venue":"Organic Letters","topic":"Synthesis and Catalytic Reactions","field":"Chemistry","cited_by":29,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"","keywords":"Intramolecular force; Chemistry; Rhodium; Ring (chemistry); Catalysis; Carbon monoxide; Medicinal chemistry; Hydrogen; Combinatorial chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002378654,0.0005204349,0.0002398705,0.000223741,0.0001438408,0.0002330645,0.0004744821,0.0002305219,0.001432801],"category_scores_gemma":[0.0002076567,0.0002347653,0.000247587,0.0001058924,0.0001995519,0.0002623949,0.0003201111,0.000417713,0.0006396485],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002585504,"about_ca_system_score_gemma":0.0003529965,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002504405,"about_ca_topic_score_gemma":0.0008511295,"domain_scores_codex":[0.9998716,0.00001747403,0.0000165216,0.00002730792,0.00002397006,0.00004302297],"domain_scores_gemma":[0.9999032,0.00001262788,0.00003796072,0.0000121595,0.00001201193,0.00002203898],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001480905,0.0000328618,0.0001228313,0.0002159259,0.00001054325,0.0004654944,0.0000768086,0.0004391818,0.9906565,0.00129347,0.0002168515,0.006321393],"study_design_scores_gemma":[0.00008508509,0.0005381863,0.001079327,0.00001404825,0.00002065859,0.0007397289,0.00002312849,0.0007004201,0.9844936,0.0001246914,0.01215349,0.00002764588],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9664661,0.004051383,0.01434257,0.0002403418,0.0001499449,0.0002428618,0.0007962425,0.0003959269,0.01331468],"genre_scores_gemma":[0.981856,0.001890928,0.0110192,0.0000809031,0.00002964723,0.0001418797,0.0003615797,0.0000393394,0.004580455],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001432801,"threshold_uncertainty_score":0.004793227,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009052182664155015,"score_gpt":0.2038350286629274,"score_spread":0.1947828459987724,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}