{"id":"W2035777841","doi":"10.1039/c1cc13323c","title":"The thiopyran route to polypropionates","year":2011,"lang":"en","type":"review","venue":"Chemical Communications","topic":"Asymmetric Synthesis and Catalysis","field":"Chemistry","cited_by":39,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Saskatchewan","funders":"","keywords":"Thiopyran; Template; Enantioselective synthesis; Aldol reaction; Combinatorial chemistry; Stereoselectivity; Stereochemistry; Chemistry; Catalysis; Nanotechnology; Organic chemistry; Materials science","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002017487,0.0003384472,0.000797653,0.00007363499,0.0004660902,0.00008891003,0.005062242,0.0003309298,0.0001310833],"category_scores_gemma":[0.0006266208,0.0002133665,0.0006680159,0.0006190566,0.0002366943,0.00003200322,0.001549342,0.0006913827,0.0006943294],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001615178,"about_ca_system_score_gemma":0.0001332857,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004898791,"about_ca_topic_score_gemma":0.000007476621,"domain_scores_codex":[0.9984942,0.00006059856,0.0006310663,0.0003308079,0.0001733601,0.000309934],"domain_scores_gemma":[0.9926435,0.001717943,0.0002712123,0.005098487,0.00008484904,0.0001839743],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"not_applicable","study_design_scores_codex":[9.123567e-7,0.00005131171,7.110038e-7,0.0004317678,0.0001680641,1.377421e-7,0.00003617728,1.575946e-9,0.00001452464,0.003164749,0.001733427,0.9943982],"study_design_scores_gemma":[0.00002325738,0.00000143658,1.480866e-7,0.001120199,0.0005858671,0.000005452975,0.00003924951,0.000001415058,0.0006402148,0.000185358,0.9971303,0.000267074],"study_design_candidate":"not_applicable","study_design_consensus":null,"genre_codex":"review","genre_gemma":"review","genre_scores_codex":[4.319129e-7,0.8504835,0.000007077086,0.0002811573,0.00002542191,0.0001236662,0.0000821412,0.00008670706,0.1489099],"genre_scores_gemma":[0.00009461898,0.9940903,0.0007611528,0.00004306399,0.0001027755,0.0005950899,0.0004167279,0.00006328286,0.003833056],"genre_candidate":"review","genre_consensus":"review","teacher_disagreement_score":0.9953969,"threshold_uncertainty_score":0.9406989,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.1056951924593471,"score_gpt":0.3433342722222915,"score_spread":0.2376390797629444,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}