{"id":"W2035816185","doi":"10.1021/ja0768800","title":"Silylene Extrusion from Organosilanes via Double Geminal Si−H Bond Activation by a Cp*Ru(κ<sup>2</sup>-<i>P</i>,<i>N</i>)<sup>+</sup> Complex:  Observation of a Key Stoichiometric Step in the Glaser−Tilley Alkene Hydrosilylation Mechanism","year":2007,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":41,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Saskatchewan; University of Alberta; Dalhousie University","funders":"","keywords":"Chemistry; Silylene; Intramolecular force; Isomerization; Ligand (biochemistry); Alkene; Hydrosilylation; Indene; Medicinal chemistry; Stereochemistry; Catalysis; Organic chemistry; Silicon","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001586374,0.000353858,0.0002416778,0.0001284926,0.0001717444,0.0002740666,0.0003001204,0.0003046891,0.001913912],"category_scores_gemma":[0.0001445351,0.0001919872,0.0002015688,0.0001627228,0.0002250751,0.0003543753,0.0003219877,0.0004240537,0.0004253024],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002953269,"about_ca_system_score_gemma":0.0001238237,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003034402,"about_ca_topic_score_gemma":0.0005676083,"domain_scores_codex":[0.9998827,0.00001528309,0.000009219958,0.00002886689,0.00002569268,0.00003821092],"domain_scores_gemma":[0.999949,0.00001156547,0.00001689056,0.000009681817,0.000004847166,0.000007987443],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001386088,0.00001826678,0.0001645937,0.00008955369,0.00001412894,0.0001527573,0.0001269028,0.0001827779,0.9958838,0.0007225883,0.0001351108,0.002370979],"study_design_scores_gemma":[0.00001026473,0.00008069768,0.0003014755,0.000001673294,0.000003103709,0.00007496822,0.00001203532,0.0002391142,0.9982014,0.00002993316,0.001042143,0.000003174646],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9926485,0.0003212563,0.003042945,0.0000640611,0.00001743202,0.00002569941,0.0001734629,0.0001471493,0.003559443],"genre_scores_gemma":[0.9970747,0.0001513685,0.001158034,0.00001624592,0.000003576765,0.000008892941,0.0001221408,0.00002097343,0.001444121],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001913912,"threshold_uncertainty_score":0.006402671,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01436237448981638,"score_gpt":0.2397189247581526,"score_spread":0.2253565502683362,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}