{"id":"W2035825227","doi":"10.1021/om048998k","title":"Reactions of an Amido Hydrido Complex of Osmium, OsH(NHCMe<sub>2</sub>CMe<sub>2</sub>NH<sub>2</sub>)(PPh<sub>3</sub>)<sub>2</sub>:  HX Addition, HX Transfer, and Ketone H<sub>2</sub> Hydrogenation","year":2005,"lang":"en","type":"article","venue":"Organometallics","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":49,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Osmium; Catalysis; Medicinal chemistry; Ketone; Ruthenium; Crystallography; Stereochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","sts","research_integrity","insufficient_payload"],"consensus_categories":["metaepi_narrow","research_integrity"],"category_scores_codex":[0.002780249,0.00394064,0.004703466,0.004330714,0.001969489,0.0007059942,0.002800436,0.003000066,0.000661311],"category_scores_gemma":[0.001295289,0.004607601,0.002593128,0.009887641,0.002200522,0.003625112,0.0008657127,0.003183286,0.001167979],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.002147641,"about_ca_system_score_gemma":0.001400334,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00009884695,"about_ca_topic_score_gemma":0.001066608,"domain_scores_codex":[0.978361,0.001022802,0.006822465,0.004962575,0.005042187,0.003788965],"domain_scores_gemma":[0.9848529,0.001333055,0.003538056,0.004686799,0.002810586,0.002778648],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0005221025,0.003964544,0.0003569547,0.00109101,0.002358754,0.0001285596,0.001284004,0.001278183,0.9063432,0.000595526,0.002312998,0.07976417],"study_design_scores_gemma":[0.006846019,0.0006276486,0.001761075,0.0004380354,0.002981669,0.0006339084,0.001095851,0.006257521,0.9687606,0.0008088061,0.005428451,0.004360387],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9818101,0.001892459,0.003717209,0.001175828,0.0007643928,0.002257669,0.004591651,0.001468222,0.002322451],"genre_scores_gemma":[0.9717922,0.01030855,0.0004734859,0.0008745493,0.001824875,0.0006688809,0.0128025,0.001166371,0.00008858803],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.07540379,"threshold_uncertainty_score":0.9996097,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01260453823165428,"score_gpt":0.219475121472981,"score_spread":0.2068705832413267,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}