{"id":"W2035825227","doi":"10.1021/om048998k","title":"Reactions of an Amido Hydrido Complex of Osmium, OsH(NHCMe<sub>2</sub>CMe<sub>2</sub>NH<sub>2</sub>)(PPh<sub>3</sub>)<sub>2</sub>:  HX Addition, HX Transfer, and Ketone H<sub>2</sub> Hydrogenation","year":2005,"lang":"en","type":"article","venue":"Organometallics","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":49,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Osmium; Catalysis; Medicinal chemistry; Ketone; Ruthenium; Crystallography; Stereochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001001746,0.0001980036,0.0001518929,0.0000707006,0.0001116412,0.0002143052,0.0001879651,0.0002267399,0.0008875782],"category_scores_gemma":[0.0001195579,0.0001192758,0.0001022029,0.00006802432,0.0001949813,0.0003101016,0.0002534075,0.0002344338,0.0001355247],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002429251,"about_ca_system_score_gemma":0.0001364903,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003408223,"about_ca_topic_score_gemma":0.0005394554,"domain_scores_codex":[0.9999377,0.000009526227,0.000003948886,0.00001085807,0.00002059591,0.00001745871],"domain_scores_gemma":[0.9999539,0.000007416974,0.00001405178,0.000005590921,0.000005051843,0.00001406924],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000200259,0.0000121813,0.0003138963,0.00005667865,0.00001112493,0.00007126724,0.00004882014,0.0001576206,0.9970486,0.0006495889,0.00006962976,0.001360293],"study_design_scores_gemma":[0.00001288698,0.0001703311,0.0008075113,0.000001308481,0.000005670365,0.0001174212,0.00001741034,0.0003826484,0.9971739,0.00006352225,0.001243951,0.000003449078],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9968381,0.0002948926,0.001126333,0.00002577013,0.00001345528,0.00001176988,0.000030256,0.00002459047,0.001634932],"genre_scores_gemma":[0.9978973,0.0001325534,0.0007365266,0.00001016058,0.00000242792,0.000005415627,0.00004444837,0.000006656979,0.001164662],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0008875782,"threshold_uncertainty_score":0.002969205,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01260453823165428,"score_gpt":0.219475121472981,"score_spread":0.2068705832413267,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}