{"id":"W2036211320","doi":"10.1039/c2cc36835h","title":"Dissociation of aryl sulfonyl phthalimide radical anions: relevance to the biological activity of aryl sulfonyl amides","year":2012,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Chemical Reaction Mechanisms","field":"Chemistry","cited_by":12,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Guelph","funders":"","keywords":"Sulfonyl; Chemistry; Aryl; Phthalimide; Phthalimides; Aryl radical; Dissociation (chemistry); Medicinal chemistry; Computational chemistry; Photochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004462809,0.0003803884,0.0002097813,0.0000971682,0.0001178507,0.0002376804,0.0003593714,0.0003805992,0.001378294],"category_scores_gemma":[0.0003385412,0.000120485,0.0001891447,0.0000704755,0.0004181136,0.0003274388,0.0001628415,0.0006015913,0.0002072243],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001876657,"about_ca_system_score_gemma":0.0001530201,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002521906,"about_ca_topic_score_gemma":0.0001540587,"domain_scores_codex":[0.9999164,0.00001980107,0.000004133055,0.00001408447,0.0000264714,0.00001901186],"domain_scores_gemma":[0.9998596,0.00006227029,0.00003499836,0.00001069534,0.00001516482,0.00001724192],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001470797,0.00002161786,0.000144226,0.0000689078,0.000003081175,0.0001173055,0.00003558973,0.0004136925,0.9964497,0.0007989969,0.00003991464,0.001759831],"study_design_scores_gemma":[0.00002355093,0.0002437466,0.0005388996,0.000003432159,0.00000494543,0.0001703921,0.00002070757,0.001123629,0.9967611,0.0002694331,0.0008346458,0.00000547498],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.988791,0.001903696,0.006712623,0.0004158538,0.00002966171,0.00003386105,0.0001105625,0.00004931275,0.001953438],"genre_scores_gemma":[0.9950497,0.001376771,0.001754386,0.00004833075,0.00002048581,0.0000222248,0.00009468262,0.000007886392,0.00162561],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001378294,"threshold_uncertainty_score":0.004610837,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.06553285262241397,"score_gpt":0.3157407253435727,"score_spread":0.2502078727211587,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}