{"id":"W2036378655","doi":"10.1039/b919920a","title":"Verdazyl radicals as redox-active, non-innocent, ligands: contrasting electronic structures as a function of electron-poor and electron-rich ruthenium bis(β-diketonate) co-ligands","year":2009,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Magnetism in coordination complexes","field":"Materials Science","cited_by":60,"is_retracted":false,"has_abstract":true,"ca_institutions":"York University; University of British Columbia; University of Victoria","funders":"","keywords":"Ruthenium; Delocalized electron; Chemistry; Redox; Radical; Ligand (biochemistry); Electron delocalization; Photochemistry; Electron; Inorganic chemistry; Organic chemistry; Catalysis; Receptor","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0004844509,0.0003415289,0.0005112812,0.0001876949,0.0004654737,0.0001297384,0.001187227,0.0002233733,0.0002483712],"category_scores_gemma":[0.0005911773,0.0003445549,0.00009784329,0.0005433785,0.0005076812,0.0003071446,0.0002327188,0.0006494835,0.00002998441],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002073826,"about_ca_system_score_gemma":0.0003727035,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00006142193,"about_ca_topic_score_gemma":0.00000976239,"domain_scores_codex":[0.9974633,0.0001208206,0.0007150676,0.0005313718,0.0004369876,0.0007324146],"domain_scores_gemma":[0.9972174,0.0006787103,0.0004350904,0.001170448,0.0003085588,0.0001898027],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002171221,0.0001636054,0.00004486813,0.00002117104,0.00003173841,4.264242e-7,0.0001790684,0.000003801425,0.9710566,0.0258312,0.0006616684,0.001788692],"study_design_scores_gemma":[0.0009764704,0.000531912,0.001077534,0.00004008766,0.00008164319,0.00003832287,0.00007089153,0.0003912807,0.9654267,0.02713838,0.003890642,0.0003361198],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9872591,0.00211934,0.0005457719,0.002389142,0.00006456723,0.0004945932,0.00003426487,0.000180231,0.006913019],"genre_scores_gemma":[0.997567,0.0005017607,0.0009415377,0.0004835259,0.00008576209,0.00006905982,0.0001442245,0.00003322052,0.000173932],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01030791,"threshold_uncertainty_score":0.9999006,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01200836270400811,"score_gpt":0.2991324828442418,"score_spread":0.2871241201402337,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}