{"id":"W2036416478","doi":"10.1021/om8008734","title":"Replacing Chloride by Alkoxide: Cp<sub>2</sub>Zr(H)OR, Searching for Alternatives to Schwartz's Reagent","year":2009,"lang":"en","type":"article","venue":"Organometallics","topic":"Radioactive element chemistry and processing","field":"Chemistry","cited_by":22,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Chemistry; Alkoxide; Regioselectivity; Yield (engineering); Metallocene; Medicinal chemistry; Moiety; Acetylacetone; Substituent; Stereochemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001932441,0.0004891118,0.0002038477,0.0001692479,0.00008501809,0.0002675173,0.000488496,0.0002505642,0.002602118],"category_scores_gemma":[0.0002272363,0.0001376121,0.0001778682,0.000164833,0.0001962247,0.0004020981,0.0003223704,0.0003323178,0.001146004],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002231935,"about_ca_system_score_gemma":0.0002931791,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008054011,"about_ca_topic_score_gemma":0.001037224,"domain_scores_codex":[0.9998647,0.00001922644,0.00001437953,0.00003528756,0.00003487063,0.00003145505],"domain_scores_gemma":[0.9999228,0.00001413868,0.00003291205,0.000009094812,0.00001187371,0.00000913743],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001181533,0.0000136484,0.0001937065,0.0002366132,0.00002163832,0.0001267773,0.00003044031,0.0001902617,0.9923459,0.0003760007,0.0001861039,0.006160693],"study_design_scores_gemma":[0.00001324216,0.0001907407,0.000296196,0.000004532738,0.00003203942,0.0002246491,0.00001799655,0.0003066185,0.9932866,0.00004835986,0.005574256,0.000004703782],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.949257,0.005736871,0.03169651,0.0003289653,0.0001894579,0.0001481513,0.000448932,0.0008287987,0.01136537],"genre_scores_gemma":[0.9760512,0.003025267,0.01285222,0.0001821748,0.00003440741,0.00003635033,0.0003357341,0.0001126909,0.007369998],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002602118,"threshold_uncertainty_score":0.00870502,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02043313091436494,"score_gpt":0.2862564900564563,"score_spread":0.2658233591420913,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}