{"id":"W2036814524","doi":"10.1021/ja901460y","title":"Characterization of β-B-Agostic Isomers in Zirconocene Amidoborane Complexes","year":2009,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Hydrogen Storage and Materials","field":"Materials Science","cited_by":99,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Agostic interaction; Characterization (materials science); Stereochemistry; Organic chemistry; Nanotechnology; Metal","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003772804,0.00009844488,0.0004258605,0.00002061832,0.00002834703,0.00001930181,0.0003638104,0.00003497963,0.00006684454],"category_scores_gemma":[0.0000782565,0.000066265,0.0002085812,0.0002707625,0.0002351952,0.0001353484,0.00004154223,0.000117576,0.000003461555],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00008152584,"about_ca_system_score_gemma":0.00005520246,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002292327,"about_ca_topic_score_gemma":3.428871e-7,"domain_scores_codex":[0.9988756,0.000073132,0.0005253501,0.00009761939,0.0002492465,0.0001790111],"domain_scores_gemma":[0.9987414,0.00004901497,0.0009199377,0.0001494612,0.00008206337,0.00005807513],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005435204,0.00007828821,0.0002170706,0.00001013502,0.000008198705,0.000001736437,0.0003753373,0.00001303138,0.9985125,0.00001259748,0.0001378196,0.0005789269],"study_design_scores_gemma":[0.0002702946,0.00007904888,0.005024729,0.00004648256,0.00001993645,0.00002201432,0.0001054654,0.00001938174,0.9939858,0.0001774137,0.000175234,0.00007419139],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9987629,0.00002497581,0.0001380053,0.0008225932,0.0001523618,0.00006094276,0.00001434147,0.000006559872,0.00001729447],"genre_scores_gemma":[0.9976919,0.00006328279,0.001188457,0.0009006882,0.0001373968,5.753513e-7,0.000001697324,0.000006560891,0.000009440417],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004807658,"threshold_uncertainty_score":0.2702208,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01079688153525182,"score_gpt":0.2517120841586262,"score_spread":0.2409152026233744,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}