{"id":"W2036949100","doi":"10.1002/chin.200241221","title":"Total Synthesis of Ionomycin Using Ring‐Opening Strategies.","year":2002,"lang":"en","type":"article","venue":"ChemInform","topic":"Synthesis and Biological Activity","field":"Biochemistry, Genetics and Molecular Biology","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Ionomycin; Ring (chemistry); Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009320196,0.0001122682,0.0001571785,0.00001755274,0.00004245768,0.00001726715,0.0001229875,0.0001297861,0.0002731339],"category_scores_gemma":[0.0001186909,0.00008906895,0.00009734809,0.00005256508,0.00007137509,0.000008641904,0.00008840348,0.0000483306,0.000007474853],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001260836,"about_ca_system_score_gemma":0.00001611429,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001825957,"about_ca_topic_score_gemma":0.000001124551,"domain_scores_codex":[0.9994166,0.000001250074,0.0001774077,0.0001645705,0.0000688263,0.0001712699],"domain_scores_gemma":[0.9996077,0.0000271439,0.00009882222,0.0001861562,0.00003308708,0.00004712286],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000213649,0.00005919356,0.0005830901,0.00002370863,0.00003465183,8.910026e-7,0.00002363605,0.00001031651,0.8542609,0.0000422812,0.0003501432,0.1445898],"study_design_scores_gemma":[0.00009270622,0.00004902914,0.000924853,0.00001773207,0.00001179387,0.00001480599,0.0001309871,0.0002446945,0.9948903,0.000009896507,0.003478829,0.0001343884],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8171241,0.0001555823,0.00002376787,0.00001475019,0.00003032767,0.00005337592,0.000007150309,0.000007503239,0.1825834],"genre_scores_gemma":[0.9988586,0.00004473734,0.0003570736,0.00002098377,0.0001051144,0.000006828112,0.000005228278,0.000006932023,0.0005945214],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1819889,"threshold_uncertainty_score":0.3632126,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0288208786255194,"score_gpt":0.2404589546987046,"score_spread":0.2116380760731852,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}