{"id":"W2037065420","doi":"10.1039/b308710g","title":"Catalytic CN bond metathesis of carbodiimides by group 4 and 5 imido complexes supported by guanidinate ligands","year":2003,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":87,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"","keywords":"Metathesis; Catalysis; Chemistry; Alkyl; Aryl; Salt metathesis reaction; Group (periodic table); Medicinal chemistry; Combinatorial chemistry; Functional group; Metal; Stereochemistry; Organic chemistry; Polymerization","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001579142,0.0004040299,0.0001977874,0.0001937506,0.0001406695,0.0002178352,0.0004579899,0.0001876333,0.001027994],"category_scores_gemma":[0.0002059732,0.0002225158,0.0001740419,0.0001099084,0.0001703257,0.0001944196,0.0002482131,0.0002968888,0.0002315597],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000392455,"about_ca_system_score_gemma":0.0001799542,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001145215,"about_ca_topic_score_gemma":0.002372123,"domain_scores_codex":[0.9998897,0.000009740439,0.000005978188,0.00002241155,0.00003477241,0.00003728295],"domain_scores_gemma":[0.9999516,0.000009512396,0.0000144168,0.000008060234,0.000006145872,0.00001024596],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001046207,0.00001969827,0.0002156429,0.0000574606,0.000008248369,0.0001064069,0.00006056543,0.000263157,0.9931372,0.0006974838,0.00009961648,0.00522982],"study_design_scores_gemma":[0.000008579462,0.00004880057,0.0004114188,0.000001714839,0.000005141091,0.00005844063,0.000006024494,0.000545968,0.9976436,0.0000300449,0.001237813,0.000002429244],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9870142,0.00118371,0.003988584,0.00005127471,0.00002365264,0.00003660016,0.00006211545,0.0001014997,0.00753834],"genre_scores_gemma":[0.9935248,0.000524516,0.002929811,0.00001494535,0.000005586617,0.0000130006,0.00009419645,0.00001887686,0.002874247],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001145215,"threshold_uncertainty_score":0.003439009,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02719378017147365,"score_gpt":0.2829575290542236,"score_spread":0.2557637488827499,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}