{"id":"W2037099530","doi":"10.1080/17415993.2011.640328","title":"A one-pot conversion of di-substituted thiourea to<i>O</i>-organyl arylthiocarbamate using FeCl<sub>3</sub>","year":2012,"lang":"en","type":"article","venue":"Journal of Sulfur Chemistry","topic":"Sulfur-Based Synthesis Techniques","field":"Chemistry","cited_by":5,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Department of Science and Technology, Ministry of Science and Technology, India; University of Regina","keywords":"Thiourea; Chemistry; Isothiocyanate; Reactivity (psychology); Phenyl isothiocyanate; Medicinal chemistry; Alcohol; Organic chemistry","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.000856947,0.0004423489,0.0008735208,0.0001638976,0.000116853,0.0000464691,0.0007231277,0.0005098106,0.0003567081],"category_scores_gemma":[0.0006461302,0.0004580994,0.0004520623,0.000388819,0.0001653874,0.0004982869,0.0001911779,0.0008287387,0.00001790411],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000467333,"about_ca_system_score_gemma":0.0003333756,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001227121,"about_ca_topic_score_gemma":3.524748e-7,"domain_scores_codex":[0.9967189,0.00004216817,0.001268639,0.0003022241,0.0009687807,0.0006992727],"domain_scores_gemma":[0.9964113,0.0002733885,0.001440583,0.000683341,0.0005622762,0.000629108],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000281779,0.0004615278,0.006935219,0.0008265963,0.0002172294,0.00004026234,0.0002906806,0.00002285889,0.9896491,0.000004363563,0.0005890643,0.0006813348],"study_design_scores_gemma":[0.0008024191,0.00002655755,0.000499036,0.001105734,0.0002820274,0.0003530224,0.0002964335,0.00002155904,0.9956092,0.00003712391,0.0005231665,0.0004437447],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9958047,0.0006268883,0.0004195359,0.0001330281,0.0001909612,0.00008722853,0.00003820167,0.0001094635,0.002589976],"genre_scores_gemma":[0.995842,0.0001582338,0.002951172,0.00009417407,0.0008112059,0.00000472014,0.00001108256,0.0000912785,0.00003616432],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006436183,"threshold_uncertainty_score":0.9997871,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02431854041638619,"score_gpt":0.247524345437274,"score_spread":0.2232058050208878,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}