{"id":"W2037289019","doi":"10.1016/j.chroma.2011.09.011","title":"Dicationic ion-pairing of phosphoric acid diesters post-liquid chromatography and subsequent determination by electrospray positive ionization-tandem mass spectrometry","year":2011,"lang":"en","type":"article","venue":"Journal of Chromatography A","topic":"Toxic Organic Pollutants Impact","field":"Environmental Science","cited_by":44,"is_retracted":false,"has_abstract":false,"ca_institutions":"Environment and Climate Change Canada; Carleton University","funders":"","keywords":"Chemistry; Chromatography; Electrospray ionization; Phosphoric acid; Mass spectrometry; Electrospray; Reagent; Selected reaction monitoring; Tandem mass spectrometry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0009969691,0.001008378,0.0005750235,0.00104188,0.0008490045,0.0005553844,0.0007663008,0.0008578463,0.008361691],"category_scores_gemma":[0.001721412,0.0005523849,0.0004556046,0.0006309942,0.0006671466,0.0008615942,0.0006938894,0.00141641,0.002108955],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005603891,"about_ca_system_score_gemma":0.001180748,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006635184,"about_ca_topic_score_gemma":0.001416954,"domain_scores_codex":[0.9990106,0.0001306995,0.00007647488,0.0002927551,0.0003321455,0.0001573347],"domain_scores_gemma":[0.9992381,0.0001492473,0.0001156096,0.0001392145,0.0002661983,0.0000915466],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0005983047,0.00008145379,0.0003588252,0.00006807503,0.00003747522,0.0000822718,0.00005278729,0.0001666078,0.989058,0.0004856205,0.0004331636,0.008577478],"study_design_scores_gemma":[0.00001879668,0.0001747187,0.0007018761,0.000004275657,0.00001536958,0.0001239738,0.00001333894,0.000736511,0.9959494,0.0001179337,0.002134016,0.000009852208],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7923666,0.003465535,0.1796993,0.0006474911,0.0006947675,0.0008809917,0.001853461,0.00280352,0.01758833],"genre_scores_gemma":[0.8852316,0.002473826,0.08494794,0.0008408474,0.0002193247,0.0008558974,0.003343125,0.0004259615,0.02166157],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.008361691,"threshold_uncertainty_score":0.02797264,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005405312409441054,"score_gpt":0.2050381596410554,"score_spread":0.1996328472316143,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}