{"id":"W2037374692","doi":"10.1002/anie.200904093","title":"Zwitterionic Relatives of Cationic Platinum Group Metal Complexes: Applications in Stoichiometric and Catalytic σ‐Bond Activation","year":2010,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Cyclopropane Reaction Mechanisms","field":"Chemistry","cited_by":67,"is_retracted":false,"has_abstract":true,"ca_institutions":"Dalhousie University","funders":"","keywords":"Cationic polymerization; Reactivity (psychology); Chemistry; Platinum group; Ligand (biochemistry); Platinum; Catalysis; Metal; Main group element; Polymer chemistry; Stoichiometry; Combinatorial chemistry; Transition metal; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001235863,0.0001657509,0.000183894,0.0004377818,0.00007856377,0.0000343874,0.0001781201,0.0001503334,0.0004365158],"category_scores_gemma":[0.0001728173,0.0001775753,0.00005989704,0.000417974,0.0001071205,0.0006197983,0.00005893229,0.0003548781,0.000009085329],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001828824,"about_ca_system_score_gemma":0.00004555587,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001252436,"about_ca_topic_score_gemma":0.00007899135,"domain_scores_codex":[0.9987664,0.000007096744,0.0003999482,0.000328464,0.000356248,0.0001417946],"domain_scores_gemma":[0.9989908,0.0002076203,0.000337568,0.0002166746,0.0001903284,0.0000569912],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002205474,0.0001251805,0.001588732,0.00007435308,0.00003533833,5.060124e-7,0.0003344817,0.000004882347,0.9906351,0.005974635,0.00003413252,0.001170635],"study_design_scores_gemma":[0.0006702057,0.00001562511,0.01177275,0.00005170223,0.00002502003,0.00001492784,0.0006062124,0.00009098841,0.9818567,0.002347681,0.002381592,0.0001666207],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9870163,0.00006498292,0.003693756,0.0002270873,0.0002948306,0.0002155662,0.0001191769,0.00006889999,0.008299454],"genre_scores_gemma":[0.9966713,0.00004195606,0.0008669993,0.00001816128,0.0003606415,0.0001537196,0.001711729,0.00002262499,0.0001529272],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01018402,"threshold_uncertainty_score":0.724131,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01258105790594799,"score_gpt":0.2568117923885915,"score_spread":0.2442307344826435,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}