{"id":"W2037454307","doi":"10.1016/s0162-0134(00)00231-2","title":"Platinum carboxylato-pendant-arm macrocycles: structure, redox properties and anti-cancer potential","year":2001,"lang":"en","type":"article","venue":"Journal of Inorganic Biochemistry","topic":"Metal complexes synthesis and properties","field":"Medicine","cited_by":18,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Prince Edward Island","funders":"Atlantic Canada Opportunities Agency","keywords":"Chemistry; Platinum; Disproportionation; Cyclic voltammetry; Redox; Reactivity (psychology); Adduct; Metal; Polymer chemistry; Medicinal chemistry; Stereochemistry; Electrochemistry; Inorganic chemistry; Organic chemistry; Catalysis; Electrode; Physical chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0000992741,0.0001560497,0.0001882438,0.0001218324,0.0001001804,0.0001837965,0.0002336581,0.00024842,0.0008208905],"category_scores_gemma":[0.0001577091,0.0001046717,0.00007430957,0.0001027163,0.00009402308,0.0001594713,0.0001229456,0.0002272495,0.0001881518],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001774019,"about_ca_system_score_gemma":0.00007922646,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002464518,"about_ca_topic_score_gemma":0.0004965414,"domain_scores_codex":[0.9999657,0.000004717558,0.000002868929,0.00001034216,0.000008574019,0.000007866995],"domain_scores_gemma":[0.9999574,0.000007586679,0.000008843205,0.000004666134,0.000006201528,0.00001533411],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004117825,0.00002876754,0.0001590367,0.00004909678,0.000008457551,0.00008914934,0.00002499462,0.0002670281,0.9876992,0.0005546447,0.0002026453,0.0105052],"study_design_scores_gemma":[0.00003345527,0.0007982621,0.00143654,0.000004229857,0.00001748118,0.0002446836,0.000008238358,0.000699153,0.9908954,0.0001199331,0.005735425,0.000007282378],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9862824,0.00622987,0.003294583,0.0002080347,0.00004944755,0.00002630717,0.0001832367,0.0001094519,0.003616594],"genre_scores_gemma":[0.992969,0.001673196,0.001474521,0.00007791835,0.00001087907,0.00002047646,0.0001432184,0.00001402464,0.003616754],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0008208905,"threshold_uncertainty_score":0.002746224,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02348422619328099,"score_gpt":0.2415779479211606,"score_spread":0.2180937217278796,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}