{"id":"W2037503778","doi":"10.1002/ejoc.201101072","title":"A Tandem “On‐Palladium” Heck–Jeffery Amination Route Toward the Synthesis of Functionalized Indole‐2‐carboxylates","year":2011,"lang":"en","type":"article","venue":"European Journal of Organic Chemistry","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":21,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"Natural Sciences and Engineering Research Council of Canada; McMaster University","keywords":"Chemistry; Amination; Intramolecular force; Heck reaction; Palladium; Indole test; Tandem; Annulation; Organic chemistry; Combinatorial chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.001611161,0.0002762581,0.0004082984,0.00007038115,0.00009105222,0.00003767529,0.000639521,0.0000886957,0.0208502],"category_scores_gemma":[0.002369835,0.0002116934,0.0003058272,0.000323051,0.0001694653,0.0001148823,0.0001141107,0.0004799198,0.00003948342],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001963205,"about_ca_system_score_gemma":0.0002104357,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000002083446,"about_ca_topic_score_gemma":3.083837e-7,"domain_scores_codex":[0.9976074,0.0001913485,0.001034571,0.000255328,0.0006935031,0.0002179095],"domain_scores_gemma":[0.9970566,0.0006359886,0.001207756,0.0004548017,0.0004945229,0.0001503221],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0005619138,0.0003760316,0.003821438,0.0003182466,0.0006781228,0.0001143825,0.001576359,0.00004835771,0.982865,0.00007442519,0.002119497,0.007446193],"study_design_scores_gemma":[0.00143689,0.00005937555,0.0103158,0.0003474195,0.0003117582,0.0005480123,0.0009028742,0.0000468723,0.9790424,0.0001934868,0.006491623,0.0003035246],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8481886,0.0006306271,0.005308816,0.0005387717,0.0006258367,0.00009512718,0.00004250015,0.00009050853,0.1444792],"genre_scores_gemma":[0.9954623,0.00007186001,0.000731873,0.00009042609,0.0007028913,0.000002257512,0.00001478242,0.00007730937,0.002846309],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1472737,"threshold_uncertainty_score":0.9800449,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03324233603993607,"score_gpt":0.2351361694715164,"score_spread":0.2018938334315803,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}