{"id":"W2037524801","doi":"10.1021/jp0489370","title":"Control of Bond Excitation and Dissociation in HCN Using Laser Pulses","year":2004,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry A","topic":"Laser-Matter Interactions and Applications","field":"Physics and Astronomy","cited_by":8,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Waterloo","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Excitation; Dissociation (chemistry); Intramolecular force; Atomic physics; Chemistry; Molecule; Redistribution (election); Triatomic molecule; Laser; Bond length; Bond energy; Ionization; Molecular physics; Physics; Stereochemistry; Optics; Ion; Physical chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006440902,0.00004414719,0.00009835414,0.000007289081,0.00003706272,0.00001199578,0.00004938325,0.000009084049,0.00001611503],"category_scores_gemma":[0.000005403785,0.00003079496,0.00004322831,0.0000596101,0.0000289463,0.0001001849,0.000007043226,0.00009847606,5.287736e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002129379,"about_ca_system_score_gemma":0.00002086656,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00007881255,"about_ca_topic_score_gemma":7.249381e-7,"domain_scores_codex":[0.9996833,0.000009876334,0.0001533628,0.00003237839,0.00007015139,0.00005090076],"domain_scores_gemma":[0.9995891,0.00007842905,0.0002078821,0.00004882939,0.00005565959,0.00002008591],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004120462,0.0004330664,0.001205051,0.00001621741,0.00005423146,3.124662e-7,0.000578426,0.01414536,0.9820116,0.0009183554,0.00002483464,0.0005714048],"study_design_scores_gemma":[0.001764326,0.00004270684,0.004807154,0.0001335955,0.0001391214,0.000007031234,0.001193554,0.004813557,0.9308929,0.05596972,0.0001246667,0.0001116919],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9920574,0.000005632731,0.007232385,0.000252714,0.000004310993,0.0000318738,0.00001236097,8.814685e-7,0.0004024565],"genre_scores_gemma":[0.9997526,4.543061e-7,0.00004489028,0.00001160976,0.0001703966,0.000001400527,0.000001802519,0.000003196582,0.00001369196],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.05505136,"threshold_uncertainty_score":0.1255782,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007353537721193489,"score_gpt":0.267986038158735,"score_spread":0.2606325004375414,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}