{"id":"W2037597083","doi":"10.1021/ja043732q","title":"Cleavage of Hydrazine and 1,1-Dimethylhydrazine by Dinuclear Tantalum Hydrides:  Formation of Imides, Nitrides, and <i>N</i>,<i>N</i>-Dimethylamine","year":2004,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":34,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"","keywords":"Chemistry; Phosphine; Dimethylamine; Bond cleavage; Hydrazine (antidepressant); Nitride; Medicinal chemistry; Cleavage (geology); Stereochemistry; Crystallography; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004237465,0.0001967069,0.0006357181,0.00005112846,0.00006487423,0.00001597026,0.0003244972,0.0000898185,0.0000191626],"category_scores_gemma":[0.0002773806,0.0001425986,0.0004047733,0.0006875778,0.0007540283,0.0002047471,0.0001694913,0.0003697329,6.110977e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001279686,"about_ca_system_score_gemma":0.00004813578,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00008568847,"about_ca_topic_score_gemma":8.129614e-7,"domain_scores_codex":[0.9982831,0.00002723724,0.000782079,0.000163444,0.0005416475,0.000202435],"domain_scores_gemma":[0.9974743,0.0001941092,0.001784849,0.00024022,0.0001598849,0.0001466154],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000684192,0.0001562153,0.0004662467,0.000106604,0.000172324,9.565696e-7,0.0003095569,0.00002107469,0.9902425,0.00001185866,0.002360599,0.006083616],"study_design_scores_gemma":[0.001235495,0.00008225971,0.0001060923,0.00008306728,0.0002030218,0.00009441692,0.0006895554,0.0003095444,0.9957377,0.000233892,0.001081693,0.0001432711],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9968526,0.001483961,0.0003341679,0.0007560001,0.00001880595,0.00004830987,0.00004924318,0.00001090425,0.0004459585],"genre_scores_gemma":[0.9957237,0.001318446,0.002554386,0.000269357,0.00006055677,0.000001121818,0.000009409947,0.00002296142,0.00004006598],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005940345,"threshold_uncertainty_score":0.5815,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004564223055006146,"score_gpt":0.2146280723175828,"score_spread":0.2100638492625766,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}