{"id":"W2037597083","doi":"10.1021/ja043732q","title":"Cleavage of Hydrazine and 1,1-Dimethylhydrazine by Dinuclear Tantalum Hydrides:  Formation of Imides, Nitrides, and <i>N</i>,<i>N</i>-Dimethylamine","year":2004,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":34,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"","keywords":"Chemistry; Phosphine; Dimethylamine; Bond cleavage; Hydrazine (antidepressant); Nitride; Medicinal chemistry; Cleavage (geology); Stereochemistry; Crystallography; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001441026,0.0003027098,0.0001563709,0.00007852029,0.0001156293,0.000146362,0.0004576847,0.0002516859,0.001133399],"category_scores_gemma":[0.0001766931,0.0001706932,0.0001393055,0.00008539412,0.0001799763,0.000220193,0.0002460001,0.0003080583,0.0002683101],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004430529,"about_ca_system_score_gemma":0.00021206,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009316565,"about_ca_topic_score_gemma":0.001594346,"domain_scores_codex":[0.9998928,0.00001420556,0.000006440624,0.00002703573,0.0000295088,0.00002994873],"domain_scores_gemma":[0.9999396,0.00001038159,0.0000201081,0.000009839199,0.000007629329,0.00001245353],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009697764,0.000008472001,0.0001434526,0.00003936908,0.000007263756,0.00008434246,0.00004972846,0.000100549,0.9975974,0.0003365054,0.00006043172,0.001475541],"study_design_scores_gemma":[0.000004732567,0.00003611381,0.0003536554,0.000001156425,0.000002657187,0.00006444482,0.00001178351,0.0002538629,0.9986571,0.00002053531,0.0005922907,0.000001636764],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9916866,0.0003818939,0.002818814,0.00005396871,0.00001935897,0.00002099155,0.0001262622,0.0000711718,0.004820835],"genre_scores_gemma":[0.9950709,0.0002205207,0.001669917,0.00001860437,0.000003009671,0.00001256326,0.0001948475,0.00002261664,0.002787194],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001133399,"threshold_uncertainty_score":0.00379163,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004564223055006146,"score_gpt":0.2146280723175828,"score_spread":0.2100638492625766,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}