{"id":"W2037935642","doi":"10.1021/ja067961j","title":"Facile Heterolytic Cleavage of Dihydrogen by Phosphines and Boranes","year":2007,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":831,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Windsor","funders":"","keywords":"Heterolysis; Chemistry; Boranes; Steric effects; Frustrated Lewis pair; Borane; Adduct; Cleavage (geology); Lewis acids and bases; Phosphine; Medicinal chemistry; Organic chemistry; Photochemistry; Catalysis; Boron","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001915313,0.0001660176,0.0004021702,0.000006248966,0.00004901632,0.00001562418,0.0003983164,0.00009028979,0.00008477727],"category_scores_gemma":[0.00009170384,0.0001137781,0.0003744579,0.0001647367,0.0006324538,0.00005623296,0.0001278162,0.0003748052,8.390251e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0000779768,"about_ca_system_score_gemma":0.00003419218,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002140141,"about_ca_topic_score_gemma":4.615854e-7,"domain_scores_codex":[0.9987943,0.000006759906,0.0004767209,0.000140567,0.0003423158,0.0002393428],"domain_scores_gemma":[0.9986801,0.0001414835,0.0007301818,0.0002253988,0.00006714224,0.000155665],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005299871,0.00008410655,0.01810695,0.00007741893,0.0000988507,0.000001876634,0.0002189967,2.717672e-7,0.968236,5.297163e-7,0.01213173,0.0009902908],"study_design_scores_gemma":[0.0004384606,0.00002167705,0.000644206,0.00003729294,0.00005918714,0.00007884197,0.000619735,0.000009076982,0.9964949,0.00002463372,0.001449826,0.0001221964],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9984072,0.0006641265,0.00001520003,0.0005662559,0.00003355488,0.00001838768,0.00002387542,0.00001272963,0.0002586725],"genre_scores_gemma":[0.9987532,0.0002380213,0.0002633705,0.0004589861,0.0001643349,2.929433e-7,0.000001344399,0.00002098349,0.0000994364],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02825889,"threshold_uncertainty_score":0.4639738,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004662995051755429,"score_gpt":0.224526987823426,"score_spread":0.2198639927716706,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}