{"id":"W2038033009","doi":"10.1021/ic991436m","title":"Syntheses, Structures, and Fluxionality of Blue Luminescent Zinc(II) Complexes:  Zn(2,2‘,2‘ ‘-tpa)Cl<sub>2</sub>, Zn(2,2‘,2‘ ‘-tpa)<sub>2</sub>(O<sub>2</sub>CCF<sub>3</sub>)<sub>2</sub>, and Zn(2,2‘,3‘ ‘-tpa)<sub>4</sub>(O<sub>2</sub>CCF<sub>3</sub>)<sub>2</sub> (tpa = Tripyridylamine)","year":2000,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Organic Light-Emitting Diodes Research","field":"Engineering","cited_by":165,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"","keywords":"Chemistry; Ligand (biochemistry); Zinc; Crystallography; Denticity; Isomerization; Octahedral molecular geometry; Stereochemistry; Octahedron; Luminescence; Crystal structure; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","sts","scholarly_communication","open_science","research_integrity","insufficient_payload"],"consensus_categories":["metaepi_narrow","sts","research_integrity"],"category_scores_codex":[0.008232881,0.01488673,0.01405597,0.004303291,0.005548791,0.003836083,0.01088616,0.01037178,0.0005525688],"category_scores_gemma":[0.006559276,0.01719275,0.005273666,0.01202845,0.007678946,0.005412673,0.007721129,0.01625133,0.002460326],"about_ca_system_candidate":true,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.009894812,"about_ca_system_score_gemma":0.00558311,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003825575,"about_ca_topic_score_gemma":0.001533472,"domain_scores_codex":[0.9369752,0.003377865,0.01512696,0.01535383,0.01303628,0.0161298],"domain_scores_gemma":[0.9594196,0.00635422,0.006339098,0.01383466,0.004747926,0.009304458],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.002908092,0.004305939,0.002505308,0.01076082,0.005198275,0.002423541,0.002900993,0.0009758187,0.9226695,0.0002104283,0.01668475,0.0284565],"study_design_scores_gemma":[0.01566964,0.001413295,0.007839316,0.005138751,0.003680118,0.004408767,0.00155349,0.004077838,0.9370828,0.0009489532,0.002650453,0.01553662],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9562056,0.01261349,0.000668272,0.001543873,0.004510739,0.009432454,0.007847582,0.006066866,0.001111133],"genre_scores_gemma":[0.9544531,0.02243473,0.0004577082,0.001374947,0.007907527,0.001921685,0.006094,0.005261374,0.00009494898],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02244436,"threshold_uncertainty_score":0.9983163,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009790077747731916,"score_gpt":0.2126864773365313,"score_spread":0.2028963995887994,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}