{"id":"W2038095920","doi":"10.1021/om3005405","title":"Switching by Photochemical<i>trans–cis</i>Isomerization of Azobenzene Substituents in Organoplatinum Complexes","year":2012,"lang":"en","type":"article","venue":"Organometallics","topic":"Photochromic and Fluorescence Chemistry","field":"Materials Science","cited_by":50,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"","keywords":"Chemistry; Isomerization; Azobenzene; Substituent; Oxidative addition; Platinum; Diimine; Cis–trans isomerism; Ligand (biochemistry); Photochemistry; Medicinal chemistry; Stereochemistry; Molecule; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002774695,0.0002042749,0.0003536136,0.00006641794,0.00005430345,0.00002675368,0.0003500822,0.0001284815,0.001648423],"category_scores_gemma":[0.00008206437,0.0002015545,0.00005013865,0.000435393,0.0000952253,0.0003807417,0.00007434442,0.0001383358,0.00005687246],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00007831644,"about_ca_system_score_gemma":0.00004355356,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004982715,"about_ca_topic_score_gemma":0.00000333356,"domain_scores_codex":[0.9984627,0.00002927355,0.0004892071,0.0002639156,0.0002986504,0.0004562151],"domain_scores_gemma":[0.9992767,0.00005386199,0.000182022,0.0002933739,0.00004535521,0.0001487115],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002040645,0.0002355458,0.01272119,0.00007515942,0.000005919097,7.24485e-7,0.0004684738,0.00000314768,0.9862429,0.00007170656,0.0001061893,0.00004860434],"study_design_scores_gemma":[0.0004338942,0.00001164286,0.001827074,0.00004281814,0.00001570583,0.00000598955,0.0000770265,0.00004658441,0.9968334,0.0000898424,0.0004012611,0.0002147453],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9949033,0.0002668396,0.003709952,0.00002009642,0.0001476443,0.0002261437,0.00006244758,0.00005177153,0.0006117853],"genre_scores_gemma":[0.9984469,0.00005053749,0.001188815,0.00006688966,0.0000573075,0.00001696787,0.00009382234,0.0000321028,0.00004669248],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01089412,"threshold_uncertainty_score":0.9992642,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00906469458887959,"score_gpt":0.2258257270277927,"score_spread":0.2167610324389131,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}