{"id":"W2038182301","doi":"10.1039/c0dt01772h","title":"Thermally triggered reductive elimination of bromine from Au(iii) as a path to Au(i)-based coordination polymers","year":2011,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Metal-Organic Frameworks: Synthesis and Applications","field":"Chemistry","cited_by":31,"is_retracted":false,"has_abstract":true,"ca_institutions":"Simon Fraser University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Bromine; Pyrazine; Isostructural; Chemistry; Aqueous solution; Coordination polymer; Polymer; Crystallography; Stereochemistry; Crystal structure; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00005179432,0.0002255868,0.000135235,0.0000559231,0.00006529829,0.0001600213,0.0002103304,0.0001720765,0.0006056865],"category_scores_gemma":[0.0001188283,0.0001286231,0.0001231858,0.00006671792,0.0001441114,0.0001643526,0.0001676783,0.0003095085,0.0001512296],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001942632,"about_ca_system_score_gemma":0.00009627586,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003509026,"about_ca_topic_score_gemma":0.0009432462,"domain_scores_codex":[0.9999301,0.000006354623,0.000003185122,0.00002191119,0.00001601046,0.00002242455],"domain_scores_gemma":[0.9999477,0.000006825708,0.00002272922,0.000004568774,0.000005612892,0.00001260682],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004923509,0.000007376363,0.00006491946,0.00004934174,0.000003560855,0.00002414661,0.0000194926,0.0001450157,0.9980863,0.00008572474,0.00003403527,0.001430778],"study_design_scores_gemma":[0.000006013834,0.0001040705,0.000556342,0.000001914508,0.00000488341,0.00005523651,0.000005901426,0.0004717126,0.9977605,0.00001485303,0.001015051,0.000003441254],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9903853,0.0008006367,0.005680406,0.00004964605,0.00001781725,0.00002471966,0.0001118582,0.0001919628,0.002737646],"genre_scores_gemma":[0.9948158,0.0002521127,0.003670393,0.00002265263,0.000003900339,0.00001586466,0.00006014713,0.00002039527,0.001138703],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0006056865,"threshold_uncertainty_score":0.0020262,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01923677628633352,"score_gpt":0.2391016024443556,"score_spread":0.2198648261580221,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}