{"id":"W2038299114","doi":"10.1021/ja036710x","title":"Regioselective Bond Cleavage in the Dissociative Electron Transfer to Benzyl Thiocyanates","year":2003,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Electrochemical Analysis and Applications","field":"Chemistry","cited_by":25,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Guelph","funders":"","keywords":"Chemistry; Regioselectivity; Dissociation (chemistry); Acetonitrile; Photochemistry; Substituent; Bond cleavage; Aryl; Moiety; Electron transfer; Thiocyanate; Medicinal chemistry; Stereochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003648826,0.0001677651,0.0003705425,0.0000139371,0.0001226669,0.00003308147,0.0006704289,0.00006581911,0.00001639073],"category_scores_gemma":[0.0001991141,0.00009246307,0.0006871501,0.001009255,0.0001880259,0.00004819519,0.00002609603,0.0009270097,0.000002600328],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003321087,"about_ca_system_score_gemma":0.00008112224,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002986321,"about_ca_topic_score_gemma":0.00001019561,"domain_scores_codex":[0.9985687,0.0000624355,0.0003959583,0.0001921313,0.0004190086,0.0003617788],"domain_scores_gemma":[0.9990155,0.0003580916,0.0002066575,0.0002438871,0.00008678987,0.00008908989],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002839808,0.0001767966,0.0009430526,0.000004741388,0.0001407096,5.734321e-7,0.001572885,0.000004371132,0.9861016,0.0005391696,0.01028119,0.0002065452],"study_design_scores_gemma":[0.0002257894,0.00003963176,0.0005164552,0.00001978048,0.00009799806,0.00001600051,0.002072285,0.000009762635,0.9903951,0.002201132,0.004273341,0.0001326869],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9910383,0.0001375063,0.0001118054,0.006046085,0.000006333221,0.00006602514,0.000005295158,0.000007020209,0.002581646],"genre_scores_gemma":[0.9969315,0.00009398742,0.0003492546,0.002403891,0.0001124176,0.00001517923,0.00000105317,0.00001506499,0.00007764091],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006007848,"threshold_uncertainty_score":0.4027447,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005843775065618476,"score_gpt":0.2466864371374187,"score_spread":0.2408426620718002,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}