{"id":"W2038427284","doi":"10.1107/s1600536806021945","title":"A monomeric <i>N</i>,<i>N</i>′-dilithiobis(amido)organophosphane","year":2006,"lang":"en","type":"article","venue":"Acta Crystallographica Section E Structure Reports Online","topic":"Organophosphorus compounds synthesis","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"","keywords":"Dilithium; Steric effects; Chemistry; Diethyl ether; Monomer; Solvent; Lithium (medication); Solvation; Medicinal chemistry; Ether; Oligomer; Ion; Stereochemistry; Crystallography; Polymer chemistry; Organic chemistry; Deprotonation; Polymer","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009768875,0.0002978111,0.0001727648,0.00008765567,0.0001971647,0.0002559123,0.0003730735,0.0002085728,0.002592884],"category_scores_gemma":[0.00008990625,0.0001561255,0.00009647961,0.0001153021,0.0001786595,0.0002258115,0.0001602645,0.0003637742,0.0009069514],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004325554,"about_ca_system_score_gemma":0.0002105835,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007084365,"about_ca_topic_score_gemma":0.001189129,"domain_scores_codex":[0.999927,0.000007562257,0.000004637592,0.00002940595,0.00001634008,0.00001497995],"domain_scores_gemma":[0.9999404,0.000006348903,0.00001568715,0.000007360812,0.000006215816,0.00002396887],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000873426,0.00001899672,0.00008568339,0.00006449736,0.000004872624,0.00005279933,0.00001420013,0.0001048684,0.9977199,0.0003605524,0.0001374951,0.001348721],"study_design_scores_gemma":[0.00002612835,0.0002548208,0.0005903855,0.000006496442,0.00001602586,0.0002038961,0.00002335927,0.0003569266,0.9881969,0.0000569756,0.01026113,0.000006839332],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9662625,0.002226385,0.006246967,0.0002047178,0.00009689679,0.00009293314,0.0009387409,0.0002515196,0.02367927],"genre_scores_gemma":[0.9786562,0.001185818,0.006376149,0.0001667504,0.00001821383,0.00008004899,0.001147714,0.00004979834,0.01231938],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002592884,"threshold_uncertainty_score":0.008674085,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004012361975491569,"score_gpt":0.1954324588432566,"score_spread":0.191420096867765,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}