{"id":"W2038481267","doi":"10.1139/v05-008","title":"3-Carboxypyridinium chlorochromate aluminium chloride An efficient and inexpensive reagent system for the selective oxidation of sulfides to sulfoxides and sulfones in solution and under microwave irradiation","year":2005,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Chemical Synthesis and Reactions","field":"Chemistry","cited_by":27,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Reagent; Sulfoxide; Pyridinium chlorochromate; Organic chemistry; Microwave irradiation; Lewis acids and bases; Chloride; Aluminium chloride; Aluminium; Catalysis","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003374656,0.0004992021,0.0002419441,0.0003162629,0.0001673549,0.000163692,0.0004029361,0.0003618026,0.001319658],"category_scores_gemma":[0.0001920608,0.0002258162,0.000192045,0.000171683,0.0002597299,0.0002657517,0.0003024493,0.0005338104,0.0004040505],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003562049,"about_ca_system_score_gemma":0.000332669,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00116122,"about_ca_topic_score_gemma":0.002082722,"domain_scores_codex":[0.9997562,0.00003883507,0.00001298546,0.00005175568,0.00009906777,0.00004125284],"domain_scores_gemma":[0.9998908,0.00002651398,0.00003069846,0.00001240215,0.00002172629,0.00001786033],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003367438,0.00000461557,0.00002619132,0.00005961863,0.000002489016,0.0000370649,0.000009128525,0.00003255002,0.9983273,0.00008501985,0.00004161869,0.001340779],"study_design_scores_gemma":[0.00001181247,0.00009675042,0.000199419,0.000002639112,0.000006144007,0.000143831,0.000004267828,0.0002072832,0.9980155,0.00001290066,0.001295997,0.000003391956],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9140326,0.004963325,0.07265873,0.0003081464,0.0001084498,0.0001694846,0.000242644,0.0006175688,0.006899127],"genre_scores_gemma":[0.9732771,0.001851903,0.02043719,0.00007291718,0.00003006985,0.0000595996,0.0002924913,0.00005420088,0.003924484],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001319658,"threshold_uncertainty_score":0.004414678,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01187020537894984,"score_gpt":0.2189470485943989,"score_spread":0.2070768432154491,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}