{"id":"W2038765843","doi":"10.1021/jo0159744","title":"Functionalized Macrocyclic Ligands for Use in Supramolecular Chemistry","year":2002,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Supramolecular Chemistry and Complexes","field":"Chemistry","cited_by":55,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Supramolecular chemistry; Chemistry; Pyridine; Molecule; Conjugated system; Self-assembly; Porphyrin; Solid-state; Coordination complex; Fluorescence; Combinatorial chemistry; Crystallography; Nanotechnology; Materials science; Photochemistry; Organic chemistry; Metal; Polymer; Physical chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0000888533,0.0003495735,0.0002140271,0.0002174928,0.0001988404,0.0003238583,0.0002861862,0.0002797382,0.002303533],"category_scores_gemma":[0.0001717011,0.0001086687,0.0001057254,0.000185977,0.0001502705,0.0002482957,0.0002583636,0.0004157347,0.001238204],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003946706,"about_ca_system_score_gemma":0.000185688,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002563269,"about_ca_topic_score_gemma":0.0005040406,"domain_scores_codex":[0.9999267,0.00001392115,0.00000545468,0.00001727371,0.00002232376,0.00001438119],"domain_scores_gemma":[0.9999315,0.00001182319,0.00001950377,0.000008546044,0.000008333614,0.00002026302],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008940669,0.0000258706,0.0001405538,0.0001167269,0.000007629304,0.0001771472,0.00002689906,0.0006689375,0.9704479,0.002629858,0.0004816127,0.02518732],"study_design_scores_gemma":[0.000020181,0.0002742181,0.000566252,0.00002177745,0.00001283285,0.0005871412,0.00001095377,0.001312073,0.9493099,0.0005718467,0.04729617,0.00001676418],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.809604,0.04566749,0.106788,0.0009545595,0.0005497006,0.0004212178,0.002243173,0.002639519,0.03113218],"genre_scores_gemma":[0.9309607,0.007197937,0.05080105,0.0004132582,0.00007341145,0.0002615578,0.001062693,0.00009575151,0.009133687],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002303533,"threshold_uncertainty_score":0.007706106,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02154000813433126,"score_gpt":0.2204010850739832,"score_spread":0.198861076939652,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}