{"id":"W2038847116","doi":"10.1021/om100334r","title":"Divergent Reactivity of Perfluoropentaphenylborole with Alkynes","year":2010,"lang":"en","type":"article","venue":"Organometallics","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":157,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta; University of Calgary","funders":"","keywords":"Diphenylacetylene; Chemistry; Pericyclic reaction; Alkyne; Adduct; Ring (chemistry); Borane; Reactivity (psychology); Medicinal chemistry; Pyridine; Stereochemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002469488,0.0005258903,0.0001858058,0.0002202413,0.000173664,0.0003867934,0.0002936406,0.000382203,0.001184781],"category_scores_gemma":[0.0002654337,0.0001664671,0.000208849,0.0001670835,0.0001957234,0.0003461909,0.0003535243,0.0003079394,0.0004400875],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002966034,"about_ca_system_score_gemma":0.0001505763,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004496456,"about_ca_topic_score_gemma":0.0008525935,"domain_scores_codex":[0.999757,0.00004823115,0.00001353062,0.00004191802,0.0000466529,0.00009265031],"domain_scores_gemma":[0.9999092,0.00002548441,0.0000239567,0.00001276997,0.00001279191,0.00001585239],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002370499,0.00002651421,0.0003600385,0.0001034949,0.00001640569,0.0002436491,0.0001093912,0.0005713429,0.9953614,0.0006527461,0.00006334544,0.002254655],"study_design_scores_gemma":[0.0000203026,0.000474829,0.0008521735,0.000008957203,0.000009885697,0.0002175407,0.00003100829,0.0006424439,0.9960256,0.0001030455,0.00160346,0.00001077555],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9948903,0.0007784567,0.0008851488,0.00002982053,0.00001029706,0.00001625021,0.00008262556,0.00003228685,0.003274813],"genre_scores_gemma":[0.9972351,0.000486845,0.0007089261,0.00001408044,0.000002170305,0.00000996032,0.00008917494,0.00001304169,0.001440741],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001184781,"threshold_uncertainty_score":0.00396353,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006752384565945911,"score_gpt":0.2055167479569353,"score_spread":0.1987643633909894,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}