{"id":"W2038847116","doi":"10.1021/om100334r","title":"Divergent Reactivity of Perfluoropentaphenylborole with Alkynes","year":2010,"lang":"en","type":"article","venue":"Organometallics","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":157,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta; University of Calgary","funders":"","keywords":"Diphenylacetylene; Chemistry; Pericyclic reaction; Alkyne; Adduct; Ring (chemistry); Borane; Reactivity (psychology); Medicinal chemistry; Pyridine; Stereochemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00009417511,0.0002681451,0.0003409092,0.00004236517,0.00008962717,0.00003168613,0.0004292656,0.0001876005,0.02151566],"category_scores_gemma":[0.00006867432,0.0002234121,0.00009629646,0.000274646,0.000232547,0.0001639782,0.0001516881,0.0004317559,0.0000784426],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002949395,"about_ca_system_score_gemma":0.0001138263,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00005895295,"about_ca_topic_score_gemma":0.00009808505,"domain_scores_codex":[0.9986601,0.000007635005,0.0002791806,0.0003902501,0.0003552904,0.0003075687],"domain_scores_gemma":[0.9986935,0.00005089181,0.0001900904,0.0007590909,0.0001149373,0.0001915249],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003813582,0.0002987222,0.04402052,0.0001054906,0.00006580754,0.000008372042,0.0001363214,5.948606e-7,0.9517622,0.0002507718,0.0001031872,0.003209883],"study_design_scores_gemma":[0.0005440359,0.00002517563,0.005774686,0.00001363692,0.00006445097,0.00003279596,0.0001556044,0.000008030563,0.9741671,0.00002813651,0.01890206,0.0002843064],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.979883,0.00007615427,0.00001547058,0.0001366294,0.0001144782,0.00005056314,0.00004826354,0.0001088497,0.01956661],"genre_scores_gemma":[0.997202,0.00005700965,0.0007521647,0.00004317793,0.0001522847,0.000006800244,0.00003781896,0.00006297995,0.001685718],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03824583,"threshold_uncertainty_score":0.9793788,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006752384565945911,"score_gpt":0.2055167479569353,"score_spread":0.1987643633909894,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}