{"id":"W2039055130","doi":"10.1023/b:rucb.0000012357.20616.15","title":"Mechanism of solid-state conversion of non-stoichiometric hydroxyapatite to diphase calcium phosphate","year":2003,"lang":"en","type":"article","venue":"Russian Chemical Bulletin","topic":"Bone Tissue Engineering Materials","field":"Engineering","cited_by":19,"is_retracted":false,"has_abstract":false,"ca_institutions":"Queen's University","funders":"","keywords":"Hydroxyapatites; Stoichiometry; Chemistry; Crystallite; Phosphate; Sintering; Solid-state; Calcium; Nuclear chemistry; Infrared spectroscopy; Crystallography; Physical chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0002050967,0.0002479012,0.0004982339,0.0002689124,0.00001446574,0.000008091809,0.0002021884,0.0001244649,0.0008343902],"category_scores_gemma":[0.000100113,0.0002613577,0.00009147973,0.0005604403,0.00003481626,0.00002609203,0.00004827214,0.0001295921,0.000264262],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006761714,"about_ca_system_score_gemma":0.00001250674,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001963855,"about_ca_topic_score_gemma":7.445034e-8,"domain_scores_codex":[0.9986308,0.00001948822,0.0005143291,0.0002264923,0.0002417977,0.0003671577],"domain_scores_gemma":[0.9992875,0.00006341999,0.00007591942,0.0003264818,0.00002765788,0.0002190608],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000200102,0.00004718062,0.000009480765,0.0003640233,0.00003747834,0.000009121218,0.0001289211,0.002666786,0.9948888,0.000528171,0.001180399,0.0001196648],"study_design_scores_gemma":[0.0005610234,0.00005141402,0.00005166675,0.000100588,0.00001966585,0.000004506317,0.000004687502,0.001262855,0.9902199,0.0000848556,0.007378499,0.0002603285],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9602306,0.0002036173,0.03613291,0.0000978711,0.0005290626,0.000348443,0.0001081568,0.0002104602,0.002138838],"genre_scores_gemma":[0.9920422,0.00002189463,0.007580497,0.00002567001,0.00002651719,0.00001746531,0.000009223618,0.00007097961,0.0002055525],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03181156,"threshold_uncertainty_score":0.9999838,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006764361795918683,"score_gpt":0.2169270067095747,"score_spread":0.210162644913656,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}