{"id":"W2039280267","doi":"10.1021/om0108548","title":"Transformations of Aryl Isocyanide on Guanidinate-Supported Organozirconium Complexes To Yield Terminal Imido, Iminoacyl, and Enediamido Ligands","year":2001,"lang":"en","type":"article","venue":"Organometallics","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":59,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"","keywords":"Chemistry; Isocyanide; Aryl; Yield (engineering); Intramolecular force; Thermal decomposition; Medicinal chemistry; Stereochemistry; Organic chemistry; Alkyl","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001381454,0.0003941965,0.0002203703,0.0001372979,0.0001309133,0.000200669,0.0004399908,0.0001763329,0.001361878],"category_scores_gemma":[0.0001836625,0.0001741709,0.0001638033,0.0001130657,0.0001749464,0.0001586315,0.0002982677,0.0004155473,0.0004487143],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003370273,"about_ca_system_score_gemma":0.0002079614,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008666517,"about_ca_topic_score_gemma":0.002323285,"domain_scores_codex":[0.9998761,0.00001712656,0.000007686875,0.00002124832,0.00003489529,0.00004288601],"domain_scores_gemma":[0.999944,0.000008609895,0.00001211925,0.00001054444,0.000009644197,0.00001506876],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001028965,0.00002067957,0.00008141162,0.0000581186,0.000006754962,0.00008837703,0.0000644819,0.0001643779,0.9960427,0.0006576436,0.00006779884,0.002644608],"study_design_scores_gemma":[0.00001593837,0.00007818321,0.0002481318,0.000002444462,0.00000535818,0.00006790291,0.00001026315,0.0002869097,0.9972368,0.00003284307,0.002010845,0.000004263392],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9838414,0.0009463264,0.005593028,0.00008091258,0.00004180731,0.00005451479,0.0001180552,0.0001578938,0.00916616],"genre_scores_gemma":[0.9898398,0.0005933908,0.004323118,0.00003496183,0.000005915302,0.00001982252,0.0001910316,0.00004705274,0.004944902],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001361878,"threshold_uncertainty_score":0.004555941,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02216245648604001,"score_gpt":0.2353381782275087,"score_spread":0.2131757217414686,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}