{"id":"W2039673659","doi":"10.1021/ac034770f","title":"Direct Electrochemical Detection of Oligonucleotide Hybridization on Poly(5-hydroxy-1,4-naphthoquinone- <i>co</i>-5-hydroxy-3-thioacetic Acid-1,4-naphthoquinone) Film","year":2003,"lang":"en","type":"letter","venue":"Analytical Chemistry","topic":"Advanced biosensing and bioanalysis techniques","field":"Biochemistry, Genetics and Molecular Biology","cited_by":48,"is_retracted":false,"has_abstract":true,"ca_institutions":"Institut National de la Recherche Scientifique","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Quinone; Naphthoquinone; Electrochemistry; Differential pulse voltammetry; Cyclic voltammetry; Covalent bond; Oligonucleotide; Combinatorial chemistry; Redox; Electrode; Polymer chemistry; Stereochemistry; DNA; Organic chemistry; Biochemistry; Physical chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001999603,0.0003606332,0.0002058028,0.0001271618,0.0001188158,0.0002819074,0.0004065208,0.0009757181,0.0007349951],"category_scores_gemma":[0.0004606913,0.0001783388,0.00008677079,0.0001264952,0.0003361431,0.0002881654,0.0001756107,0.0004686829,0.0007661087],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004040599,"about_ca_system_score_gemma":0.00008797589,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002025398,"about_ca_topic_score_gemma":0.0005172781,"domain_scores_codex":[0.9997644,0.00005362121,0.00001086617,0.00006067549,0.00008282631,0.00002764862],"domain_scores_gemma":[0.999823,0.000088872,0.00002016481,0.0000129144,0.00003517992,0.00001986841],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001636655,0.00001075311,0.00009247646,0.00003884268,0.000001541184,0.0002008975,0.00002198944,0.00002280549,0.9965116,0.0001607258,0.0001246517,0.002797292],"study_design_scores_gemma":[0.00001525158,0.0001582446,0.0009097536,0.00000699883,0.000007579104,0.001095784,0.00002266916,0.001328268,0.9896312,0.0002058298,0.006612428,0.000005983632],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"other","genre_scores_codex":[0.9001076,0.007223357,0.0764647,0.003330731,0.0007205166,0.0001302792,0.0002187817,0.0005599519,0.01124413],"genre_scores_gemma":[0.9399978,0.003224421,0.04374513,0.0009960983,0.0002352087,0.0001083727,0.0002374315,0.00003477328,0.01142083],"genre_candidate":"other","genre_consensus":null,"teacher_disagreement_score":0.0009757181,"threshold_uncertainty_score":0.002931654,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007772716939477493,"score_gpt":0.2500142489867407,"score_spread":0.2422415320472632,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}