{"id":"W2039876539","doi":"10.1039/b610079a","title":"Pyridinyloxazolidines: versatile scaffolds for chiral catalyst construction","year":2006,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":17,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Steric effects; Oxazoline; Intermolecular force; Catalysis; Ligand (biochemistry); Hydrolysis; Solid-state; Chemistry; Combinatorial chemistry; Chiral ligand; Stereochemistry; Organic chemistry; Enantioselective synthesis; Molecule","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00006973628,0.0001683639,0.0001876277,0.0001920068,0.0003383678,0.00004616132,0.0001293112,0.0001370307,0.001530848],"category_scores_gemma":[0.000008539348,0.0001808405,0.0002597271,0.0004808739,0.00007874904,0.0001439546,0.000002790997,0.00007357795,0.000052635],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001172453,"about_ca_system_score_gemma":0.00005665717,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002815763,"about_ca_topic_score_gemma":0.0001573612,"domain_scores_codex":[0.9989163,0.000006851327,0.0003149964,0.0002998608,0.000203259,0.0002587805],"domain_scores_gemma":[0.999397,0.00006772506,0.00009965255,0.0002629143,0.00009134361,0.00008140288],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000626636,0.003110527,0.003694841,0.001350903,0.002012349,0.00002340585,0.001631165,0.01819504,0.4330822,0.03663936,0.02086463,0.4787689],"study_design_scores_gemma":[0.00225489,0.00002799053,0.0001186802,0.00001829671,0.0004595917,0.0000531373,0.0009754925,0.008494642,0.8181548,0.001081545,0.1678033,0.0005576606],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"methods","genre_gemma":"empirical","genre_scores_codex":[0.3990185,0.0003586896,0.4622525,0.001088362,0.001006628,0.000517414,0.002273226,0.001123471,0.1323612],"genre_scores_gemma":[0.9908411,0.00001600132,0.001232279,0.00003023053,0.0002430192,0.0001317617,0.001003962,0.00002983338,0.006471834],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.5918226,"threshold_uncertainty_score":0.9993819,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008839945513668658,"score_gpt":0.2252648902240952,"score_spread":0.2164249447104266,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}