{"id":"W2039904681","doi":"10.1021/la9005967","title":"Chiral Thiol-Stabilized Silver Nanoclusters with Well-Resolved Optical Transitions Synthesized by a Facile Etching Procedure in Aqueous Solutions","year":2009,"lang":"en","type":"article","venue":"Langmuir","topic":"Nanocluster Synthesis and Applications","field":"Materials Science","cited_by":153,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto; Wilfrid Laurier University","funders":"","keywords":"Nanoclusters; Aqueous solution; Thiol; Well-defined; Etching (microfabrication); Materials science; Transition metal; Chemical engineering; Nanotechnology; Chemistry; Polymer chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002673923,0.0002472987,0.0003520511,0.00009027351,0.0003545923,0.0001190802,0.00031078,0.0001288796,0.0003014937],"category_scores_gemma":[0.00003638545,0.0001939592,0.00009105622,0.0003049904,0.0001160001,0.0002278907,0.00003017913,0.0001910079,0.0001372654],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00008104619,"about_ca_system_score_gemma":0.00007750515,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00005781831,"about_ca_topic_score_gemma":0.0002189813,"domain_scores_codex":[0.9982151,0.00009878629,0.0003522264,0.0004878725,0.0002749958,0.0005710493],"domain_scores_gemma":[0.9993056,0.0001177482,0.0000791475,0.0003356875,0.00003743032,0.000124358],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001778658,0.0004802047,0.00004532683,0.00003049934,0.00001056751,0.00001373346,0.001996285,0.0001813795,0.9908575,0.002596691,0.002087839,0.001522073],"study_design_scores_gemma":[0.01477623,0.001240131,0.01137638,0.001191007,0.0005387171,0.0004448309,0.007046061,0.01430533,0.8928542,0.00636753,0.04529145,0.004568131],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9743678,0.0002895372,0.007785148,0.009834778,0.00005215937,0.0009419878,0.0001669238,0.0003373023,0.006224344],"genre_scores_gemma":[0.9939343,0.000007369768,0.004726039,0.0005690536,0.00004617569,0.0001930662,0.00003571107,0.00002354712,0.0004647497],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.09800334,"threshold_uncertainty_score":0.7909426,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008774126230528782,"score_gpt":0.2167799726034181,"score_spread":0.2080058463728894,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}