{"id":"W2040095421","doi":"10.1021/ic9911926","title":"Syntheses, Molecular Structures, and Vibrational Spectra of Chloropentacarbonylrhodium(III) and -iridium(III) Undecafluorodiantimonate(V), [Rh(CO)<sub>5</sub>Cl][Sb<sub>2</sub>F<sub>11</sub>]<sub>2</sub>and [Ir(CO)<sub>5</sub>Cl][Sb<sub>2</sub>F<sub>11</sub>]<sub>2</sub>:  An Experimental and Density Functional Study","year":2000,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Inorganic Fluorides and Related Compounds","field":"Chemistry","cited_by":17,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"","keywords":"Chemistry; Monoclinic crystal system; Isostructural; Iridium; Crystallography; Orthorhombic crystal system; Infrared spectroscopy; Crystal structure; Lewis acids and bases; Bond length; Stereochemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","sts","scholarly_communication","research_integrity"],"consensus_categories":["metaepi_narrow","sts","research_integrity"],"category_scores_codex":[0.002244341,0.006743739,0.005731159,0.001252252,0.003543532,0.002285028,0.003108331,0.005110418,0.0004427624],"category_scores_gemma":[0.0006040316,0.007536927,0.001730209,0.002978821,0.003795362,0.00284493,0.002563687,0.006398134,0.0002555714],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.003177341,"about_ca_system_score_gemma":0.002743071,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002369359,"about_ca_topic_score_gemma":0.0005282477,"domain_scores_codex":[0.9724586,0.000992267,0.006312314,0.008810963,0.005690781,0.005735058],"domain_scores_gemma":[0.9847495,0.001444194,0.003291456,0.005063783,0.001453287,0.003997773],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.002777966,0.003747421,0.004743849,0.001522981,0.003020253,0.002077246,0.002067422,0.0002853198,0.969412,0.0001663279,0.002606297,0.007572871],"study_design_scores_gemma":[0.01336858,0.0009311413,0.008257511,0.001126215,0.002541974,0.005329303,0.0029952,0.001027657,0.9559382,0.0009058235,0.0002047177,0.007373646],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9824209,0.007959533,0.0002161714,0.0004661626,0.001548269,0.003262153,0.001692282,0.001446353,0.0009881429],"genre_scores_gemma":[0.9832767,0.007419406,0.0001640309,0.000755612,0.003232263,0.000499299,0.003012093,0.00160255,0.00003809157],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01347382,"threshold_uncertainty_score":0.9989157,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007735395910186893,"score_gpt":0.209467453841257,"score_spread":0.2017320579310701,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}