{"id":"W2040421464","doi":"10.1021/om0109511","title":"Improved One-Pot Synthesis of Second-Generation Ruthenium Olefin Metathesis Catalysts","year":2001,"lang":"en","type":"article","venue":"Organometallics","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":59,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Carbene; Olefin metathesis; Catalysis; Metathesis; IMes; Nucleophile; Ruthenium; Salt metathesis reaction; Combinatorial chemistry; Reagent; Olefin fiber; Ligand (biochemistry); Organic chemistry; Medicinal chemistry; Polymerization","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002745332,0.0006603722,0.0008747594,0.0003926709,0.0001692086,0.0004035233,0.0006841756,0.0004326828,0.001600022],"category_scores_gemma":[0.000306312,0.000261268,0.0004319423,0.0003017224,0.0001471446,0.0004327684,0.0003808872,0.001097818,0.0009767662],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004093411,"about_ca_system_score_gemma":0.0002691964,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002890324,"about_ca_topic_score_gemma":0.000681103,"domain_scores_codex":[0.9997612,0.00002370645,0.00002485789,0.00005229336,0.00007316004,0.00006475153],"domain_scores_gemma":[0.9998798,0.00002384659,0.00001827036,0.00003550746,0.00001963466,0.00002284686],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005769039,0.00004357919,0.00005705554,0.00007584041,0.0000131035,0.0001056203,0.00002343418,0.0003954186,0.9919673,0.0005269649,0.0001632784,0.006570768],"study_design_scores_gemma":[0.00002167333,0.00007603241,0.0002756196,0.000002247016,0.00001364396,0.0001641531,0.00000446197,0.0006260453,0.9955462,0.00006604003,0.003194693,0.000009138324],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"methods","genre_scores_codex":[0.8682495,0.005413282,0.1077411,0.0005119358,0.0002928668,0.0004166949,0.001948051,0.001847387,0.01357914],"genre_scores_gemma":[0.9376257,0.002185314,0.0488951,0.000053323,0.00004352519,0.0001459731,0.001349418,0.0001976528,0.009504013],"genre_candidate":"methods","genre_consensus":null,"teacher_disagreement_score":0.001600022,"threshold_uncertainty_score":0.005352616,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03200621229222717,"score_gpt":0.2522648288713867,"score_spread":0.2202586165791595,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}