{"id":"W2040883618","doi":"10.1021/ic011001a","title":"Insertion of SO<sub>2</sub> into the S−S Bond of Cp<sub>2</sub>MoS<sub>2</sub> and Cp<sub>2</sub>MoS<sub>2</sub>O To Give Molybdocene Dithiosulfate and Bis(<i>O</i>-alkylthiosulfates)","year":2002,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Organometallic Compounds Synthesis and Characterization","field":"Chemistry","cited_by":9,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"","keywords":"Chemistry; Crystal (programming language); Ligand (biochemistry); Bond length; Crystallography; Crystal structure; X-ray crystallography; Stereochemistry; Physics; Diffraction","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00004760482,0.0002653467,0.0001566521,0.0001269317,0.0001232398,0.0002040967,0.0002818575,0.0001749209,0.002831143],"category_scores_gemma":[0.00008293089,0.0001592019,0.0001385249,0.000190248,0.0001562822,0.0002106487,0.0002818303,0.0003515931,0.0005441536],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003621828,"about_ca_system_score_gemma":0.0003386517,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001526233,"about_ca_topic_score_gemma":0.003714938,"domain_scores_codex":[0.9999485,0.000003827108,0.000002754775,0.00001105143,0.00001932792,0.00001450585],"domain_scores_gemma":[0.9999609,0.000003871718,0.00001794926,0.000003936771,0.000003909251,0.000009298369],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002514637,0.00002253374,0.0004814006,0.0001146185,0.00001901685,0.0001607484,0.00004688156,0.0003585514,0.9909507,0.0008524245,0.0006352773,0.006106236],"study_design_scores_gemma":[0.00004744721,0.0003678607,0.002792641,0.000008447685,0.0000190003,0.0003444339,0.00005949238,0.0011453,0.9760489,0.0001892132,0.0189634,0.00001384456],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9850609,0.0006442924,0.003059793,0.0001011109,0.00004984637,0.00005918935,0.000575856,0.0002317156,0.01021734],"genre_scores_gemma":[0.9857141,0.0006055536,0.005047829,0.0000898916,0.00001349203,0.00006465234,0.001000853,0.00005581374,0.007407788],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002831143,"threshold_uncertainty_score":0.009471059,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007250815865179785,"score_gpt":0.1844982353696586,"score_spread":0.1772474195044789,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}