{"id":"W2040888967","doi":"10.1021/om701264z","title":"Steric Impact of Neutral N,N-Chelates on the Structure and Stability of Five-Coordinate Platinum(IV) Complexes: <i>fac</i>-Pt<sup>IV</sup>Me<sub>3</sub> Complexes of BAB and BAM","year":2008,"lang":"en","type":"article","venue":"Organometallics","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":31,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"","keywords":"Chemistry; Steric effects; Platinum; Chelation; Ligand (biochemistry); Crystallography; Stereochemistry; Inorganic chemistry; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001474051,0.0001538065,0.0001302931,0.00005670412,0.0001269957,0.0002695287,0.0002311469,0.0001648922,0.001553612],"category_scores_gemma":[0.0003821997,0.0001045579,0.00004782687,0.00005677332,0.0003074932,0.0001544335,0.0001909755,0.0001672072,0.0002287203],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002627454,"about_ca_system_score_gemma":0.0001393347,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006324156,"about_ca_topic_score_gemma":0.0008269697,"domain_scores_codex":[0.9999164,0.00002573948,0.000005844539,0.00001575442,0.00001745132,0.00001880151],"domain_scores_gemma":[0.9998591,0.00004883581,0.00004076982,0.000008627772,0.00001681704,0.0000258098],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0007745955,0.00001564573,0.0004675763,0.00007020112,0.00001072821,0.00009081504,0.00007795027,0.00047681,0.9950559,0.0004178245,0.00007869083,0.002463319],"study_design_scores_gemma":[0.00003067213,0.0002199778,0.001312925,0.000004047936,0.00001443758,0.0001029284,0.00003702692,0.000963875,0.9963595,0.00004740135,0.0009012433,0.000005931701],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9976456,0.0002240873,0.0003902497,0.0000263513,0.000004331541,0.000003211315,0.00002946788,0.0000234334,0.001653317],"genre_scores_gemma":[0.9993508,0.00008046596,0.0001516207,0.00001348561,0.000001361462,0.000002593372,0.00003210486,0.000006275024,0.0003613414],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001553612,"threshold_uncertainty_score":0.005197406,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01684277877404536,"score_gpt":0.2179883229908083,"score_spread":0.2011455442167629,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}