{"id":"W2040997486","doi":"10.1021/jp066868e","title":"Thermal Stability Study of Aryl Modified Carbon Black by in Situ Generated Diazonium Salt","year":2007,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry C","topic":"Synthesis and properties of polymers","field":"Materials Science","cited_by":181,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université du Québec à Montréal","funders":"","keywords":"Thermogravimetric analysis; X-ray photoelectron spectroscopy; Chemistry; Thermal stability; Aryl; Carbon fibers; Covalent bond; Polymer chemistry; Inorganic chemistry; Organic chemistry; Alkyl; Materials science; Chemical engineering","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.001263498,0.0001285266,0.0003233333,0.00001235463,0.00003101064,0.00001247106,0.0004193905,0.00004331805,0.00005241369],"category_scores_gemma":[0.00007875107,0.0000758496,0.00006876297,0.0001091594,0.000179976,0.00006635925,0.00005797924,0.0002198498,0.000001495418],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00005453602,"about_ca_system_score_gemma":0.00004782823,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001988088,"about_ca_topic_score_gemma":0.00001231544,"domain_scores_codex":[0.9987173,0.00008169281,0.0004656649,0.000111295,0.000396643,0.0002273706],"domain_scores_gemma":[0.9990157,0.0002412253,0.0003236506,0.0002496174,0.00009056685,0.00007918169],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0005447838,0.0009053616,0.0002873226,0.00002215175,0.00001663697,0.000003563523,0.002593583,0.000683727,0.9947808,5.314413e-7,0.00002105498,0.0001404534],"study_design_scores_gemma":[0.0005211316,0.0001858768,0.001418956,0.00001672039,0.00003418476,0.000001506663,0.001787983,0.0003073459,0.9956201,0.00001774509,0.000002068912,0.00008634175],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9988112,0.0001283895,0.00000381465,0.00007074235,0.00004703167,0.00008237781,0.000003098938,0.00000524792,0.0008480647],"genre_scores_gemma":[0.9997317,0.000003269009,0.0000036397,0.0000127985,0.0002145483,6.883688e-7,3.625413e-7,0.00001002267,0.0000229965],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001184747,"threshold_uncertainty_score":0.3093057,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01943656802971465,"score_gpt":0.2444083466358884,"score_spread":0.2249717786061737,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}