{"id":"W2041001820","doi":"10.1021/om700653t","title":"Enhanced Reactivity Results in Reduced Catalytic Performance:  Unexpected Ligand Reactivity of a Bis(<i>N</i>-2,6-diisopropylphenylperflourophenyl-amidate)titanium-bis(diethylamido) Hydroamination Precatalyst","year":2007,"lang":"en","type":"article","venue":"Organometallics","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":58,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"","keywords":"Hydroamination; Chemistry; Markovnikov's rule; Reactivity (psychology); Nucleophile; Ligand (biochemistry); Medicinal chemistry; Intramolecular force; Substituent; Alkene; Amine gas treating; Catalysis; Photochemistry; Stereochemistry; Organic chemistry; Regioselectivity","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001198032,0.0002609053,0.0002161056,0.00009804853,0.0001043825,0.0002858527,0.000384844,0.0002685883,0.0007044188],"category_scores_gemma":[0.0001899987,0.0001675053,0.0001323227,0.00009134049,0.0001836817,0.0001655244,0.0001676646,0.0003488104,0.0002356741],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003041528,"about_ca_system_score_gemma":0.0001896208,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004799263,"about_ca_topic_score_gemma":0.001024371,"domain_scores_codex":[0.9998695,0.00001414035,0.00001148561,0.00003147819,0.0000412137,0.00003225655],"domain_scores_gemma":[0.9998963,0.00001801737,0.00003604483,0.00001145614,0.00001783734,0.00002037747],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003282326,0.000003702819,0.00004858797,0.0000160631,0.000002514639,0.0000358977,0.000008584542,0.0000474733,0.9991498,0.00007172794,0.00001383863,0.0005690185],"study_design_scores_gemma":[0.000003362854,0.0000522853,0.0001810817,5.917545e-7,0.000002746551,0.00006690338,0.000002659541,0.0001545256,0.9991972,0.00000524854,0.0003321214,0.000001273689],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9943488,0.0004102893,0.002986972,0.00004589859,0.000009315264,0.00001815921,0.00007681767,0.00008429887,0.00201939],"genre_scores_gemma":[0.9961035,0.0001881691,0.002263575,0.00001531936,0.000002631412,0.000009346692,0.0001030113,0.00002215619,0.001292341],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0007044188,"threshold_uncertainty_score":0.00235647,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0114563884420345,"score_gpt":0.2371482810849127,"score_spread":0.2256918926428782,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}