{"id":"W2041510841","doi":"10.1039/b307308d","title":"Reactions of free radicals with η<sup>3</sup>-allylpalladium(<scp>ii</scp>) complexes: phenyl and trityl radicals","year":2003,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":14,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"","keywords":"Chemistry; Radical; Palladium; Medicinal chemistry; Thermal decomposition; Ligand (biochemistry); Benzene; Decomposition; Photochemistry; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001532025,0.0005223891,0.000260779,0.0001839722,0.0001715141,0.0003043906,0.0004853626,0.0004289391,0.002674883],"category_scores_gemma":[0.000160071,0.0001683144,0.0002368398,0.0001771406,0.000248587,0.0003355273,0.0003628893,0.0005275076,0.0005266977],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003659022,"about_ca_system_score_gemma":0.0001502861,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004385873,"about_ca_topic_score_gemma":0.0006079936,"domain_scores_codex":[0.999824,0.00002254056,0.00001051965,0.000040962,0.00003436963,0.00006777453],"domain_scores_gemma":[0.9998913,0.00002100167,0.00003409158,0.000015235,0.00001484823,0.00002345068],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003751969,0.00002757395,0.0002020188,0.0002512822,0.00004242471,0.0001421309,0.0001101197,0.0002772931,0.9951148,0.0005156591,0.0001967553,0.002744622],"study_design_scores_gemma":[0.00002199819,0.0001925479,0.0002884087,0.00000434892,0.00001128476,0.00008262861,0.00001605798,0.0002151677,0.9974778,0.00004645657,0.001636847,0.000006451852],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9921942,0.001832272,0.002301796,0.00007260605,0.00004807646,0.00004129155,0.0001945974,0.0001155965,0.003199731],"genre_scores_gemma":[0.9948631,0.000697489,0.001066844,0.00003878885,0.0000105932,0.00003268431,0.0002586623,0.00003199411,0.002999813],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002674883,"threshold_uncertainty_score":0.008948386,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01388007278190725,"score_gpt":0.2185146184626727,"score_spread":0.2046345456807654,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}