{"id":"W2042624536","doi":"10.1039/c2ob07165g","title":"Kinetics studies of rapid strain-promoted [3 + 2]-cycloadditions of nitrones with biaryl-aza-cyclooctynone","year":2012,"lang":"en","type":"article","venue":"Organic & Biomolecular Chemistry","topic":"Click Chemistry and Applications","field":"Chemistry","cited_by":53,"is_retracted":false,"has_abstract":true,"ca_institutions":"National Research Council Canada; University of Ottawa; Steacie Institute for Molecular Sciences","funders":"","keywords":"Chemistry; Kinetics; Strain (injury)","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001006044,0.000370375,0.0005048803,0.00003027816,0.00009833102,0.00001042025,0.0004032371,0.0002439965,0.00320663],"category_scores_gemma":[0.0001673006,0.000354614,0.0001636291,0.0005069587,0.0005759641,0.00007351232,0.0001498539,0.0002479528,0.00001162405],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00007152567,"about_ca_system_score_gemma":0.0000745454,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000004282794,"about_ca_topic_score_gemma":8.419298e-7,"domain_scores_codex":[0.9981449,0.00001386653,0.0006057271,0.0003835956,0.0003825636,0.0004693568],"domain_scores_gemma":[0.998001,0.0001089392,0.0004554202,0.0009468641,0.0002770678,0.0002107573],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002930803,0.0008368675,0.0002385885,0.001087839,0.0004112943,0.000007123778,0.0002245233,5.574635e-7,0.9963954,0.00002830813,0.0002679103,0.0004722473],"study_design_scores_gemma":[0.0007366754,0.00003103332,0.00007420011,0.0002040522,0.0002859682,0.0001247518,0.001042337,0.00000411845,0.9956874,0.00008089382,0.001363227,0.0003653326],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9853054,0.002885833,0.003001336,0.0002343115,0.00003000965,0.0001318258,0.0008647834,0.0001316586,0.007414846],"genre_scores_gemma":[0.997192,0.0002321632,0.001183544,0.00001876662,0.0002013273,0.00004449569,0.0005593104,0.0000645852,0.000503773],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01188664,"threshold_uncertainty_score":0.9998906,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01761765063974171,"score_gpt":0.2586395550399868,"score_spread":0.2410219044002451,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}