{"id":"W2043163575","doi":"10.1063/1.1337047","title":"IR spectroscopy of aqueous alkali halide solutions: Pure salt-solvated water spectra and hydration numbers","year":2001,"lang":"en","type":"article","venue":"The Journal of Chemical Physics","topic":"Spectroscopy and Quantum Chemical Studies","field":"Physics and Astronomy","cited_by":161,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université du Québec à Trois-Rivières","funders":"","keywords":"Chemistry; Aqueous solution; Salt (chemistry); Alkali metal; Halide; Inorganic chemistry; Ion; Chloride; Water of crystallization; Spectral line; Solvated electron; Infrared spectroscopy; Analytical Chemistry (journal); Physical chemistry; Radiolysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004528387,0.0008370043,0.0004514907,0.0009275768,0.0002663057,0.0003074419,0.000598432,0.0003209827,0.001796686],"category_scores_gemma":[0.0008078811,0.0003662039,0.0003037445,0.0007229473,0.0002649781,0.0007211157,0.0005877729,0.0007446904,0.0006177612],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000151248,"about_ca_system_score_gemma":0.0001770795,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005503697,"about_ca_topic_score_gemma":0.0005344694,"domain_scores_codex":[0.9996927,0.00002951019,0.00002331418,0.00005708834,0.0001700437,0.00002735171],"domain_scores_gemma":[0.9995639,0.0001068384,0.00006104939,0.00003905682,0.0001929556,0.00003634938],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005754127,0.00001172892,0.0004512694,0.00005742204,0.000008213972,0.00002331718,0.00008427936,0.0001459658,0.9965051,0.0000654004,0.00003596718,0.002553875],"study_design_scores_gemma":[0.00001014783,0.00008188796,0.005603334,0.000008573493,0.00002666178,0.00007411159,0.0001061567,0.002950674,0.9900181,0.0001244123,0.0009833656,0.00001264765],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9465519,0.001443609,0.04564755,0.00006359892,0.00003382329,0.0001299357,0.0006364142,0.0006614979,0.004831759],"genre_scores_gemma":[0.9585364,0.001537452,0.03482383,0.00009203763,0.00002009469,0.0002734649,0.001056028,0.0002925988,0.003368113],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001796686,"threshold_uncertainty_score":0.006010532,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01256500621291387,"score_gpt":0.2460676368413283,"score_spread":0.2335026306284144,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}