{"id":"W2043277036","doi":"10.1002/ejoc.200600440","title":"Stereoselective Glycosylations Using (<i>R</i>)‐ or (<i>S</i>)‐(Ethoxycarbonyl)benzyl Chiral Auxiliaries at C‐2 of Glycopyranosyl Donors","year":2006,"lang":"en","type":"article","venue":"European Journal of Organic Chemistry","topic":"Carbohydrate Chemistry and Synthesis","field":"Chemistry","cited_by":48,"is_retracted":false,"has_abstract":true,"ca_institutions":"Institute for Biological Sciences","funders":"RIKEN; National Institutes of Health","keywords":"Chemistry; Stereoselectivity; Glycosylation; Carbonium ion; Anomer; Glycosyl; Glycosidic bond; Glycosyl donor; Chiral auxiliary; Stereochemistry; Alkoxy group; Glycoside; Organic chemistry; Ion; Enantioselective synthesis; Alkyl; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0004984983,0.0004679322,0.0007235763,0.00006462443,0.000227766,0.0000730634,0.0006869072,0.0001555851,0.008254076],"category_scores_gemma":[0.0003408596,0.0004202072,0.0004399443,0.0003835437,0.0003083443,0.0002061439,0.0002237513,0.0005936273,0.00001402152],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004135916,"about_ca_system_score_gemma":0.0003720587,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001813162,"about_ca_topic_score_gemma":0.00001274176,"domain_scores_codex":[0.996955,0.00009677823,0.001520145,0.0003962501,0.0005625749,0.0004693005],"domain_scores_gemma":[0.9970322,0.0002612977,0.001507105,0.0005734853,0.0004029627,0.0002229035],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0006126782,0.0002038762,0.001759105,0.0003150353,0.0001899856,0.0003715367,0.0002650883,0.0001369341,0.9955869,0.000004495088,0.0003702129,0.0001841856],"study_design_scores_gemma":[0.001532812,0.00004035144,0.0002825865,0.0002756149,0.000289173,0.001353484,0.0003625878,0.00008117905,0.9929141,0.00009151825,0.002344609,0.0004319552],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9454128,0.0005099284,0.0001971067,0.00005997201,0.0001205034,0.00004074181,0.00007563185,0.00004972868,0.0535336],"genre_scores_gemma":[0.9896966,0.00005186127,0.0008878838,0.0000184796,0.001045841,7.406817e-7,0.00002275941,0.0001182207,0.008157586],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.04537601,"threshold_uncertainty_score":0.999825,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01478777608805094,"score_gpt":0.2139898979426778,"score_spread":0.1992021218546268,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}