{"id":"W2043277036","doi":"10.1002/ejoc.200600440","title":"Stereoselective Glycosylations Using (<i>R</i>)‐ or (<i>S</i>)‐(Ethoxycarbonyl)benzyl Chiral Auxiliaries at C‐2 of Glycopyranosyl Donors","year":2006,"lang":"en","type":"article","venue":"European Journal of Organic Chemistry","topic":"Carbohydrate Chemistry and Synthesis","field":"Chemistry","cited_by":48,"is_retracted":false,"has_abstract":true,"ca_institutions":"Institute for Biological Sciences","funders":"RIKEN; National Institutes of Health","keywords":"Chemistry; Stereoselectivity; Glycosylation; Carbonium ion; Anomer; Glycosyl; Glycosidic bond; Glycosyl donor; Chiral auxiliary; Stereochemistry; Alkoxy group; Glycoside; Organic chemistry; Ion; Enantioselective synthesis; Alkyl; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000269818,0.0003686378,0.0002509321,0.0001291934,0.00009965103,0.0002970701,0.0002970489,0.0001673627,0.001227809],"category_scores_gemma":[0.0002012713,0.0001441402,0.0002165953,0.0001786918,0.0001978628,0.000320312,0.000346535,0.0004815769,0.0004493842],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002428035,"about_ca_system_score_gemma":0.0002130181,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002958093,"about_ca_topic_score_gemma":0.0005546699,"domain_scores_codex":[0.9998857,0.00002507698,0.000009039689,0.00002245026,0.00002237822,0.00003528568],"domain_scores_gemma":[0.9999015,0.00001313726,0.00004489085,0.00001650587,0.000008374834,0.00001559008],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002077061,0.00002877407,0.0001105607,0.00004539788,0.000007061208,0.000141767,0.00002613583,0.0004175747,0.994058,0.001319338,0.000111037,0.003526497],"study_design_scores_gemma":[0.00002617654,0.0001933589,0.0002646057,0.000003123868,0.000007536563,0.0000956786,0.000007652853,0.0007522946,0.9969356,0.0001122067,0.001595706,0.000006082087],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9802353,0.000617163,0.0108882,0.0001060995,0.00005765419,0.00006701845,0.0002048144,0.0001807935,0.007643024],"genre_scores_gemma":[0.9912012,0.0005478269,0.005770233,0.00004881624,0.00001403488,0.00001701767,0.0001349819,0.00004068598,0.00222515],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001227809,"threshold_uncertainty_score":0.004107416,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01478777608805094,"score_gpt":0.2139898979426778,"score_spread":0.1992021218546268,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}