{"id":"W2043402556","doi":"10.1021/jp071070w","title":"Core/Shell Formation of Gold Nanoparticles Induced on Exposure to <i>N</i>,<i>N</i>-Dimethylformamide:  Chemical and Morphological Changes","year":2007,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry C","topic":"Nanomaterials and Printing Technologies","field":"Engineering","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"Polytechnique Montréal; Regroupement Québécois sur les Matériaux de Pointe","funders":"","keywords":"Nanoparticle; Coalescence (physics); Materials science; Chemical engineering; Substrate (aquarium); Nanotechnology; Formamide; Shell (structure); Chemistry; Composite material; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000433999,0.0001143998,0.0002233322,0.00002406651,0.00001771285,0.0000104052,0.0002174882,0.00008231847,0.000003458342],"category_scores_gemma":[0.00009957144,0.00007203754,0.00004203825,0.0001115305,0.00006100154,0.00005447078,0.00006506622,0.0002120163,0.000002009978],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002530109,"about_ca_system_score_gemma":0.000004046158,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000001047946,"about_ca_topic_score_gemma":2.067451e-7,"domain_scores_codex":[0.999337,0.000009082555,0.0002677662,0.00005181532,0.0001651082,0.0001692562],"domain_scores_gemma":[0.9994892,0.0001530559,0.0001028231,0.0001371569,0.00005374013,0.0000640435],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009201356,0.00003466924,0.000007402014,0.00006281898,0.00001079835,0.000004093087,0.0001892499,0.0003704992,0.9961299,0.00002114255,0.0001195952,0.002957817],"study_design_scores_gemma":[0.0002017504,0.0002416362,0.0001507382,0.00005486205,0.00001918674,0.00005761749,0.000105225,0.0001988652,0.9984055,0.0004116315,0.00007099351,0.00008204822],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9994494,0.00006238815,0.00005189337,0.0001448076,0.000036664,0.000052843,0.000003847643,0.00004973398,0.0001484713],"genre_scores_gemma":[0.9995503,0.00002659579,0.0002183853,0.00003155124,0.0001594631,0.000001014899,5.397899e-7,0.000009326764,0.000002791809],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002875768,"threshold_uncertainty_score":0.2937605,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0270084761594059,"score_gpt":0.2445146014751458,"score_spread":0.2175061253157398,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}